Modern synthetic approaches to phosphorus-sulfur bond formation in organophosphorus compounds

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Modern synthetic approaches to phosphorus-sulfur bond formation in organophosphorus compounds

Jones, David J.; O'Leary, Eileen M.; O'Sullivan, Timothy P.
Date: 2020-06-12
Copyright: © 2020, WILEY‐VCH Verlag GmbH & Co. This is the peer reviewed version of the following article: Jones, D. J., O'Leary, E. M. and O'Sullivan, T. P. (2020) 'Modern synthetic approaches to phosphorus-sulfur bond formation in organophosphorus compounds', Advanced Synthesis and Catalysis, 362(14), pp. 2801-2846, doi: 10.1002/adsc.202000458, which has been published in final form at https://doi.org/10.1002/adsc.202000458. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Full text restriction information: Access to this article is restricted until 12 months after publication by request of the publisher.
Restriction lift date: 2021-06-12
Citation: Jones, D. J., O'Leary, E. M. and O'Sullivan, T. P. (2020) 'Modern synthetic approaches to phosphorus-sulfur bond formation in organophosphorus compounds', Advanced Synthesis and Catalysis, 362(14), pp. 2801-2846. doi: 10.1002/adsc.202000458
Published Version: 10.1002/adsc.202000458

Abstract:

Phosphorothioates, phosphonothioates, phosphinothioates and phosphonodithioates are organophosphorus compounds with widespread application, especially in the fields of agrochemicals, medicinal chemistry and materials chemistry. Herein, we review modern methods for the construction of the phosphorus-sulfur bonds in these important functional groups. This review is organised on the basis of the different synthetic approaches, with the advantages and disadvantages of each also examined.

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