Modern synthetic approaches to phosphorus-sulfur bond formation in organophosphorus compounds

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Date
2020-06-12
Authors
Jones, David J.
O'Leary, Eileen M.
O'Sullivan, Timothy P.
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John Wiley & Sons, Inc.
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Abstract
Phosphorothioates, phosphonothioates, phosphinothioates and phosphonodithioates are organophosphorus compounds with widespread application, especially in the fields of agrochemicals, medicinal chemistry and materials chemistry. Herein, we review modern methods for the construction of the phosphorus-sulfur bonds in these important functional groups. This review is organised on the basis of the different synthetic approaches, with the advantages and disadvantages of each also examined.
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Organophosphorus chemistry , Organosulfur chemistry , Phosphinothioate , Phosphonodithioate , Phosphonothioate , Phosphorothioate , Phosphorus-sulfur bond formation
Citation
Jones, D. J., O'Leary, E. M. and O'Sullivan, T. P. (2020) 'Modern synthetic approaches to phosphorus-sulfur bond formation in organophosphorus compounds', Advanced Synthesis and Catalysis, 362(14), pp. 2801-2846. doi: 10.1002/adsc.202000458
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© 2020, WILEY‐VCH Verlag GmbH & Co. This is the peer reviewed version of the following article: Jones, D. J., O'Leary, E. M. and O'Sullivan, T. P. (2020) 'Modern synthetic approaches to phosphorus-sulfur bond formation in organophosphorus compounds', Advanced Synthesis and Catalysis, 362(14), pp. 2801-2846, doi: 10.1002/adsc.202000458, which has been published in final form at https://doi.org/10.1002/adsc.202000458. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.