Asymmetric oxidation of sulfides

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dc.contributor.author O'Mahony, Graham E.
dc.contributor.author Ford, Alan
dc.contributor.author Maguire, Anita R.
dc.date.accessioned 2016-08-16T14:43:23Z
dc.date.available 2016-08-16T14:43:23Z
dc.date.issued 2012-10-16
dc.identifier.citation O'Mahony, G. E., Ford, A. and Maguire, A. R. (2013) 'Asymmetric oxidation of sulfides'. Journal of Sulfur Chemistry, 34(3), pp. 301-341. http://dx.doi.org/10.1080/17415993.2012.725247 en
dc.identifier.volume 34 en
dc.identifier.issued 3 en
dc.identifier.startpage 301 en
dc.identifier.endpage 341 en
dc.identifier.issn 1741-5993
dc.identifier.issn 1741-6000
dc.identifier.uri http://hdl.handle.net/10468/2996
dc.identifier.doi 10.1080/17415993.2012.725247
dc.description.abstract This review discusses synthesis of enantiopure sulfoxides through the asymmetric oxidation of prochiral sulfides. The use of metal complexes to promote asymmetric sulfoxidation is described in detail, with a particular emphasis on the synthesis of biologically active sulfoxides. The use of non-metal-based systems, such as oxaziridines, chiral hydroperoxides and peracids, as well as enzyme-catalyzed sulfoxidations is also examined. en
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher Taylor and Francis en
dc.rights © 2013 Taylor and Francis Group, LLC. This is a Submitted Manuscript of an article published by Taylor & Francis in Journal of Sulfur Chemistry on 16 Oct 2012, available online: http://www.tandfonline.com/10.1080/17415993.2012.725247. en
dc.subject Sulfide oxidation en
dc.subject Sulfoxides en
dc.subject Asymmetric synthesis en
dc.subject Enantioselective synthesis en
dc.subject Metal-based catalysts en
dc.subject Alkyl aryl sulfides en
dc.subject Chiral schiff-bases en
dc.subject Helminthosporium species NRRL-4671 en
dc.subject Optically-active sulfoxides en
dc.subject Benzyl methyl sulfoxides en
dc.subject Aqueous hydrogen-peroxide en
dc.subject Tert-butyl hydroperoxide en
dc.subject Twin coronet porphyrins en
dc.subject Mandelic-acid complex en
dc.subject Bovine serum-albumin en
dc.title Asymmetric oxidation of sulfides en
dc.type Article (peer-reviewed) en
dc.internal.authorcontactother Anita Maguire, Vice President For Research, University College Cork, Cork, Ireland. +353-21-490-3000 Email: a.maguire@ucc.ie en
dc.internal.availability Full text available en
dc.date.updated 2016-08-16T13:58:56Z
dc.description.version Submitted Version en
dc.internal.rssid 243944759
dc.internal.wokid 000318150600011
dc.description.status Peer reviewed en
dc.identifier.journaltitle Journal of Sulfur Chemistry en
dc.internal.copyrightchecked Yes en
dc.internal.licenseacceptance Yes en
dc.internal.IRISemailaddress a.maguire@ucc.ie en


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