Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds

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dc.contributor.author Slattery, Catherine N.
dc.contributor.author Clarke, Leslie-Ann
dc.contributor.author O'Neill, Shane T.
dc.contributor.author Ring, Aoife
dc.contributor.author Ford, Alan
dc.contributor.author Maguire, Anita R.
dc.date.accessioned 2016-08-16T15:19:01Z
dc.date.available 2016-08-16T15:19:01Z
dc.date.issued 2012-01
dc.identifier.citation Slattery, C. N., Clarke, L. A., O'Neill, S., Ring, A., Ford, A. and Maguire, A. R. (2012) 'Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds', Synlett, 23(5), pp. 765-767. DOI: 10.1055/s-0031-1290598 en
dc.identifier.volume 23 en
dc.identifier.issued 5 en
dc.identifier.startpage 765 en
dc.identifier.endpage 767 en
dc.identifier.issn 0936-5214
dc.identifier.issn 1437-2096
dc.identifier.uri http://hdl.handle.net/10468/2997
dc.identifier.doi 10.1055/s-0031-1290598
dc.description.abstract Significant enhancements in enantioselectivities and reaction efficiencies in asymmetric copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds in the presence of various group I salts are reported. For the first time in carbenoid chemistry, evidence for the critical role of the metal cation is described. en
dc.description.sponsorship Irish Research Council for Science, Engineering and Technology (Programme for Research in Third Level Institutions Cycle 4); Eli Lilly and Company, United States en
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher Georg Thieme Verlag en
dc.rights © Georg Thieme Verlag Stuttgart · New York en
dc.subject C-H insertion en
dc.subject Buchner reaction en
dc.subject Diazocarbonyl en
dc.subject Copper catalysis en
dc.subject Bis(oxazoline) ligands en
dc.subject Carbene insertion en
dc.subject Bonds en
dc.subject Complexes en
dc.title Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds en
dc.type Article (peer-reviewed) en
dc.internal.authorcontactother Anita Maguire, Vice President For Research, University College Cork, Cork, Ireland. +353-21-490-3000 Email: a.maguire@ucc.ie en
dc.internal.availability Full text available en
dc.date.updated 2013-01-08T12:15:19Z
dc.description.version Accepted Version en
dc.internal.rssid 146554673
dc.internal.wokid 000301343400017
dc.contributor.funder Irish Research Council for Science Engineering and Technology en
dc.contributor.funder Eli Lilly and Company, United States en
dc.description.status Peer reviewed en
dc.identifier.journaltitle Synlett en
dc.internal.copyrightchecked No. !!CORA!! Yes en
dc.internal.licenseacceptance Yes en
dc.internal.IRISemailaddress a.maguire@ucc.ie en
dc.identifier.articleid D62911ST


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