Investigation of DMAB oxidation at a gold microelectrode in base

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dc.contributor.author Rohan, James F.
dc.contributor.author Nagle, Lorraine C.
dc.date.accessioned 2017-02-28T15:56:13Z
dc.date.available 2017-02-28T15:56:13Z
dc.date.issued 2005-04-01
dc.identifier.citation Nagle, L. C. and Rohan, J. F. (2005) 'Investigation of DMAB Oxidation at a Gold Microelectrode in Base', Electrochemical and Solid-State Letters, 8(5), pp. C77-C80. doi:10.1149/1.1883905 en
dc.identifier.volume 8 en
dc.identifier.startpage C77 en
dc.identifier.endpage C80 en
dc.identifier.issn 1099-0062
dc.identifier.uri http://hdl.handle.net/10468/3709
dc.identifier.doi 10.1149/1.1883905
dc.description.abstract A gold microdisk has been used to determine the diffusion coefficient Formula for dimethylamine borane (DMAB) in concentrated alkaline solution. Two steady-state oxidation waves were resolved through the use of microelectrodes. Using the Formula value determined, the coulomb number for both oxidation waves was shown to be 3. The first wave may be further resolved in dilute solutions revealing three one-electron steps. The concentration range wherein the maximum coulombic efficiency for DMAB oxidation on gold may be achieved is demonstrated. An oxidation pathway with a variable coulomb number is suggested. en
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher Electrochemical Society en
dc.rights © 2005 The Electrochemical Society. en
dc.subject Organic compounds en
dc.subject Gold en
dc.subject Oxidation en
dc.subject Electrochemical electrodes en
dc.subject Diffusion en
dc.subject Electrochemical analysis en
dc.subject Discs (structures) en
dc.title Investigation of DMAB oxidation at a gold microelectrode in base en
dc.type Article (peer-reviewed) en
dc.internal.authorcontactother James Rohan, Tyndall Microsystems, University College Cork, Cork, Ireland. +353-21-490-3000 Email: james.rohan@tyndall.ie en
dc.internal.availability Full text available en
dc.date.updated 2017-02-28T15:51:37Z
dc.description.version Accepted Version en
dc.internal.rssid 243942347
dc.internal.wokid 000228326600013
dc.contributor.funder Irish Research Council for Science, Engineering and Technology en
dc.description.status Peer reviewed en
dc.identifier.journaltitle Electrochemical and Solid State Letters en
dc.internal.copyrightchecked No !!CORA!! en
dc.internal.licenseacceptance Yes en
dc.internal.IRISemailaddress james.rohan@tyndall.ie en


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