Term-dependent hybridization of the 5 f-wave functions of Ba and Ba++

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Term-dependent hybridization of the 5 f-wave functions of Ba and Ba++

Connerade, J. P.; Mansfield, Michael W. D.
Date: 1982
Copyright: © 1982, American Physical Society
Related: https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.48.131
Citation: Connerade, J. P. and Mansfield, M. W. D. (1982) ' Term-dependent hybridization of the 5 f-wave functions of Ba and Ba++', Physical Review Letters, 48(3), 131-134 (4pp). doi: 10.1103/PhysRevLett.48.131
Published Version: 10.1103/PhysRevLett.48.131

Abstract:

It is shown that, unlike in neutral Ba, the 4d→5f transitions cannot be neglected in the interpretation of the 4d spectrum of Ba++. A term-dependent hybridization of the 5f wave functions occurs, the effects of which reverse between Ba and Ba++, and oscillator strength reappears in the 4d→nf (n>~5) transitions. A second kind of wave-function collapse is identified and its effects are described.

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