Effect of annealing on the development of fully transparent ternary V-O-Na-Si mixed metal oxide thin films from polymer-assisted dip-coated V2O5

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dc.contributor.author O'Hanlon, Sally
dc.contributor.author Glynn, Colm
dc.contributor.author O'Dwyer, Colm
dc.date.accessioned 2018-02-19T16:56:34Z
dc.date.available 2018-02-19T16:56:34Z
dc.date.issued 2015-10-07
dc.identifier.citation O'Hanlon, S., Glynn, C. and O'Dwyer, C. (2016) 'Effect of Annealing on the Development of Fully Transparent Ternary V-O-Na-Si Mixed Metal Oxide Thin Films from Polymer-Assisted Dip-Coated V2O5', ECS Journal of Solid State Science and Technology, 5(1), pp. R3100-R3106. doi:10.1149/2.0141601jss en
dc.identifier.volume 5 en
dc.identifier.issued 1 en
dc.identifier.startpage R3100 en
dc.identifier.endpage R3106 en
dc.identifier.issn 2162-8769
dc.identifier.uri http://hdl.handle.net/10468/5485
dc.identifier.doi 10.1149/2.0141601jss
dc.description.abstract Both transparent oxides and transparent conductive oxides are of particular research interest for future applications in flexible, optically transparent thin film transistors and luminescent devices. We report the formation of a transparent oxide material based on the interdiffusion of Na-O and Si-O species with dip-coated V2O5 thin films on a borosilicate glass substrate. The deposition process used a facile solution processed dip-coating technique in the high-rate draining regime. Liquid precursors of vanadium alkoxide and alkoxide-polyethylene glycol mixtures were used for thin film deposition. We examine the effect of annealing condition on the phase conversion process, morphology and optical transmittance due to the conversion of the V2O5 films to completely transparent ternary mixed metal oxide thin films. The work also examines the role of polymer-assisted deposition on the development of the V-O-Na-Si transparent thin films during different annealing conditions. Polymer-assisted V2O5 thin films on glass are shown to convert to optically clear thin films during annealing, with a transparency >95% across the visible spectrum, and a blue-shift of the absorption edge to maintain >90% transparency at 380 nm. en
dc.description.sponsorship Irish Research Council (Award RS/2011/797; Irish Research Council New Foundations Award); Science Foundation Ireland ((SFI) under the National Access Programme (NAP 417)) en
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher Electrochemical Society en
dc.rights © The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.0141601jss] All rights reserved. en
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0/ en
dc.subject Deposition en
dc.subject Dip-coating en
dc.subject Displays en
dc.subject Doping en
dc.subject Metal oxide en
dc.subject Spectroscopy en
dc.subject Thin films en
dc.subject Transparency en
dc.subject Vanadium oxide en
dc.title Effect of annealing on the development of fully transparent ternary V-O-Na-Si mixed metal oxide thin films from polymer-assisted dip-coated V2O5 en
dc.type Article (peer-reviewed) en
dc.internal.authorcontactother Colm O'Dwyer, Chemistry, University College Cork, Cork, Ireland. +353-21-490-3000 Email: c.odwyer@ucc.ie en
dc.internal.availability Full text available en
dc.date.updated 2018-02-19T09:06:09Z
dc.description.version Published Version en
dc.internal.rssid 320503845
dc.contributor.funder Irish Research Council en
dc.contributor.funder Science Foundation Ireland en
dc.description.status Peer reviewed en
dc.identifier.journaltitle ECS Journal of Solid State Science and Technology en
dc.internal.copyrightchecked Yes en
dc.internal.licenseacceptance Yes en
dc.internal.IRISemailaddress c.odwyer@ucc.ie en
dc.relation.project info:eu-repo/grantAgreement/SFI/SFI Technology and Innovation Development Award (TIDA)/13/TIDA/E2761/IE/LiONSKIN - Moldable Li-ion battery outer skin for electronic devices/ en
dc.relation.project info:eu-repo/grantAgreement/SFI/SFI Investigator Programme/14/IA/2581/IE/Diffractive optics and photonic probes for efficient mouldable 3D printed battery skin materials for portable electronic devices/ en


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© The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.0141601jss] All rights reserved. Except where otherwise noted, this item's license is described as © The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.0141601jss] All rights reserved.
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