Synthesis of enantioenriched sulfoxides

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dc.contributor.author O'Mahony, Graham E.
dc.contributor.author Kelly, Padraig
dc.contributor.author Lawrence, Simon E.
dc.contributor.author Maguire, Anita R.
dc.date.accessioned 2012-05-29T15:50:00Z
dc.date.available 2012-05-29T15:50:00Z
dc.date.copyright 2011-03-12
dc.date.issued 2011-03-12
dc.identifier.citation O'MAHONY, G.E., KELLY, P., LAWRENCE, S.E., MAGUIRE, A.R., 2011. Synthesis of enantioenriched sulfoxides. ARKIVOC, 1-110. en
dc.identifier.volume 2011 en
dc.identifier.issued i en
dc.identifier.startpage 1 en
dc.identifier.endpage 110 en
dc.identifier.issn 1551-7012
dc.identifier.uri http://hdl.handle.net/10468/597
dc.description.abstract This review discusses strategies for the asymmetric synthesis of sulfoxides, compounds with many applications in stereoselective synthesis and in some cases with pharmaceutical application. The review describes asymmetric oxidation, including metal catalyzed and non-metal and biological oxidation processes, in addition to synthetic approaches via nucleophilic substitution of appropriately substituted precursors. Kinetic resolution in oxidation of sulfoxides to the analogous sulfones is also discussed; in certain instances, access to enantioenriched sulfoxides can be achieved via a combination of asymmetric sulfide oxidation and complementary kinetic resolution in sulfoxide oxidation. en
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher ARKAT USA en
dc.relation.uri http://www.arkat-usa.org/get-file/38487/
dc.relation.uri http://www.arkat-usa.org/arkivoc-journal/browse-arkivoc/2011/1/
dc.rights ©ARKAT-USA, Inc. en
dc.subject Sulfide oxidation en
dc.subject Sulfoxides en
dc.subject Asymmetric synthesis en
dc.subject Enantioselective synthesis en
dc.subject Kinetic resolution en
dc.title Synthesis of enantioenriched sulfoxides en
dc.type Review en
dc.internal.authorurl http://publish.ucc.ie/researchprofiles/V001/amaguire en
dc.internal.authorcontactother Department of Chemistry and School of Pharmacy, Analytical and Biological Chemistry Research Facility, University College Cork, Cork, Ireland. T.: +353 (0)21 4901694 en
dc.internal.availability Full text available en
dc.description.version Published Version en
dc.internal.rssid 119669225
dc.description.status Peer reviewed en
dc.identifier.journaltitle Arkivoc en
dc.internal.copyrightchecked Checked publisher website: Electronic Storage Material from ARKIVOC may be stored and used electronically free of charge by any individual or organization but resale of electronically stored material requires permission of the Publisher. Used Contact Us form twice to clarity policy and contact UMich publishing office re use. http://www.arkat-usa.org/arkivoc-journal/about-arkivoc/ en
dc.internal.IRISemailaddress a.maguire@ucc.ie en


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