Synthesis and electrochemical properties of vanadium oxide materials and structures as Li-ion battery positive electrodes

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dc.contributor.author McNulty, David
dc.contributor.author Buckley, D. Noel
dc.contributor.author O'Dwyer, Colm
dc.date.accessioned 2018-05-15T12:50:57Z
dc.date.available 2018-05-15T12:50:57Z
dc.date.issued 2014-06-20
dc.identifier.citation McNulty, D., Buckley, D. N. and O'Dwyer, C. (2014) 'Synthesis and electrochemical properties of vanadium oxide materials and structures as Li-ion battery positive electrodes', Journal of Power Sources, 267, pp. 831-873. en
dc.identifier.volume 267 en
dc.identifier.startpage 831 en
dc.identifier.endpage 873 en
dc.identifier.issn 0378-7753
dc.identifier.uri http://hdl.handle.net/10468/6110
dc.identifier.doi 10.1016/j.jpowsour.2014.05.115
dc.description.abstract The electrochemical intercalation of lithium into vanadium pentoxide was first reported in the 1970's. Over the last 40 years vanadium oxides have continued to be the subject of much research due to their desirable physical properties. Initial results with bulk V2O5 and V2O5 gels demonstrated the potential for application as a cathode material for lithium batteries. Encouraging specific capacities exceeding 250 mAh g−1 were accompanied by severe capacity fading, which prevented widespread commercial application of V2O5-containing cathodes. Following the commercial release of the Li-ion battery, the development of layered materials that reversibly intercalated lithium, and the resurgence in nanoscale materials for Li-ion and alternative batteries, have opened new opportunities for the examination of the influence of material structure on cell performance. Recent decades have witnessed advances in the control of shape, structure and function of Li-ion battery materials. This review details the synthesis and structural properties of vanadium oxides, one of the model layered battery materials, and reviews the synthesis and structure of vanadium oxides and related polymorphs, bronzes and phases. Their electrochemical characteristics under a wide range of conditions are assessed and compared as positive electrode materials in lithium and lithium-ion batteries up to the present day. en
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher Elsevier en
dc.relation.uri http://www.sciencedirect.com/science/article/pii/S0378775314008088
dc.rights © 2014 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license. en
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject Li-ion batteries en
dc.subject Vanadium oxide en
dc.subject Nanomaterials en
dc.subject Electrochemistry en
dc.subject Energy storage en
dc.title Synthesis and electrochemical properties of vanadium oxide materials and structures as Li-ion battery positive electrodes en
dc.type Article (peer-reviewed) en
dc.internal.authorcontactother Colm O'Dwyer, Chemistry, University College Cork, Cork, Ireland. +353-21-490-3000 Email: c.odwyer@ucc.ie en
dc.internal.availability Full text available en
dc.date.updated 2018-05-03T10:59:20Z
dc.description.version Submitted Version en
dc.internal.rssid 260537308
dc.description.status Peer reviewed en
dc.identifier.journaltitle Journal of Power Sources en
dc.internal.copyrightchecked Yes en
dc.internal.licenseacceptance Yes en
dc.internal.IRISemailaddress c.odwyer@ucc.ie en


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©  2014 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license. Except where otherwise noted, this item's license is described as © 2014 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license.
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