Ligand design for long-range magnetic order in metal-organic frameworks
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Date
2014-09-23
Authors
Tiana, Davide
Hendon, Christopher H.
Walsh, Aron
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry (RSC)
Published Version
Abstract
We report a class of ligands that are candidates to construct metal-organic frameworks with long-range magnetic order between transition metal centres. Direct quantum chemical calculations predict Neel temperatures exceeding 100 K for the case of Mn.
Description
Keywords
Spin-exchange interactions , Pyrophosphate , (VO)(2)P2O7 , Challenges , Devices , Room
Citation
Tiana, D., Hendon, C. H. and Walsh, A. (2014) 'Ligand design for long-range magnetic order in metal-organic frameworks', Chemical Communications, 50(90), pp. 13990-13993. doi: 10.1039/c4cc06433j