The rotationally-resolved absorption spectrum of formaldehyde from 6547 to 6804 cm(-1)

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dc.contributor.author Staak, Michael
dc.contributor.author Gas, Edward G.
dc.contributor.author Venables, Dean S.
dc.contributor.author Ruth, Albert A.
dc.date.accessioned 2012-11-08T14:37:13Z
dc.date.available 2012-11-08T14:37:13Z
dc.date.copyright 2004
dc.date.issued 2005-01
dc.identifier.citation Michael Staak, Edward W. Gash, Dean S. Venables, Albert A. Ruth, The rotationally-resolved absorption spectrum of formaldehyde from 6547 to 6804 cm(−1), Journal of Molecular Spectroscopy, Volume 229, Issue 1, January 2005, Pages 115-121, ISSN 0022-2852, 10.1016/j.jms.2004.08.019. en
dc.identifier.volume 229 en
dc.identifier.issued 11 en
dc.identifier.startpage 115 en
dc.identifier.endpage 121 en
dc.identifier.issn 0022-2852
dc.identifier.uri http://hdl.handle.net/10468/747
dc.identifier.doi 10.1016/j.jms.2004.08.019
dc.description.abstract The room temperature absorption spectrum of formaldehyde, H2CO, from 6547 to 6804 cm(-1) (1527-1470 nm) is reported with a spectral resolution of 0.001 cm(-1). The spectrum was measured using cavity-enhanced absorption spectroscopy (CEAS) and absorption cross-sections were calculated after calibrating the system using known absorption lines of H2O and CO2. Several vibrational combination bands occur in this region and give rise to a congested spectrum with over 8000 lines observed. Pressure broadening coefficients in N-2, O-2, and H2CO are reported for an absorption line at 6780.871 cm(-1) and in N-2 for an absorption line at 6684.053 cm(-1). en
dc.description.sponsorship Higher Education Authority (2nd cycle, AC3 Environ. Chem.); Irish Research Council for Science Engineering and Technology (SC/2002/160) en
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher Elsevier en
dc.relation.uri http://www.sciencedirect.com/science/article/pii/S0022285204002735
dc.rights Copyright © 2004 Elsevier Inc. All rights reserved. NOTICE: this is the author’s version of a work that was accepted for publication in Journal of Molecular Spectroscopy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Molecular Spectroscopy, Volume 229, Issue 1, January 2005, Pages 115-121, ISSN 0022-2852, 10.1016/j.jms.2004.08.019. en
dc.subject Formaldehyde en
dc.subject Near infrared spectrum en
dc.subject Combination bands en
dc.subject Cavity-enhanced absorption spectroscopy en
dc.subject Pressure broadening en
dc.subject High resolution en
dc.subject H2CO en
dc.title The rotationally-resolved absorption spectrum of formaldehyde from 6547 to 6804 cm(-1) en
dc.type Article (peer-reviewed) en
dc.internal.authorurl http://publish.ucc.ie/researchprofiles/D004/dvenables en
dc.internal.authorcontactother Dean Venables, Chemistry, University College Cork, Cork, Ireland. +353-21-490-3000 Email: d.venables@ucc.ie en
dc.internal.availability Full text available en
dc.date.updated 2012-10-25T10:59:34Z
dc.description.version Accepted Version en
dc.internal.rssid 67924419
dc.contributor.funder Higher Education Authority en
dc.contributor.funder Irish Research Council for Science Engineering and Technology en
dc.description.status Peer reviewed en
dc.identifier.journaltitle Journal of Molecular Spectroscopy en
dc.internal.copyrightchecked Yes en
dc.internal.licenseacceptance Yes en
dc.internal.IRISemailaddress d.venables@ucc.ie en


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