Mo doped TiO<sub>2</sub>: impact on oxygen vacancies, anatase phase stability and photocatalytic activity
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Date
2020-02-10
Authors
Kumaeavel, Vignesh
Rhatigan, Stephen
Mathew, Snehamol
Michel, Marie Clara
Bartlett, John
Nolan, Michael
Hinder, Steven
Gascó, Antonio
Ruiz-Palomar, César
Hermosilla, Daphne
Journal Title
Journal ISSN
Volume Title
Publisher
IOP Publishing
Published Version
Abstract
This work outlines an experimental and theoretical investigation of the effect of molybdenum (Mo) doping on the oxygen vacancy formation and photocatalytic activity of TiO2. Analytical techniques such as X-ray diffraction (XRD), Raman, X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL) were used to probe the anatase to rutile transition (ART), surface features and optical characteristics of Mo doped TiO2 (Mo-TiO2). XRD results showed that the anatase to rutile transition was effectively impeded by 2 mol % Mo doping up to 750 °C, producing 67 % anatase and 33 % rutile. Moreover, the crystal growth of TiO2 was affected by Mo doping via its interaction with oxygen vacancies and the Ti—O bond. The formation of Ti—O—Mo and Mo—Ti—O bonds were confirmed by XPS results. Phonon confinement, lattice strain and non-stoichiometric defects were validated through the Raman analysis. DFT results showed that, after substitutional doping of Mo at a Ti site in anatase, the Mo oxidation state is Mo6+ and empty Mo-s states emerge at the titania conduction band minimum. The empty Mo-d states overlap the anatase conduction band in the DOS plot. A large energy cost, comparable to that computed for pristine anatase, is required to reduce Mo-TiO2 through oxygen vacancy formation. Mo5+ and Ti3+ are present after the oxygen vacancy formation and occupied states due to these reduced cations emerge in the energy gap of the titania host. PL studies revealed that the electron-hole recombination process in Mo-TiO2 was exceptionally lower than that of TiO2 anatase and rutile. This was ascribed to introduction of 5s gap states below the CB of TiO2 by the Mo dopant. Moreover, the photo-generated charge carriers could easily be trapped and localized on the TiO2 surface by Mo6+ and Mo5+ ions to improve the photocatalytic activity.
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Keywords
Photocatalysis , Ceramics , Dopant , XPS , Titania
Citation
Vignesh, K., Stephen, R., Snehamol, M., Marie Clara, M., John, B., Michael, N., Steven, H., Antonio, G., César, R.-P., Daphne, H. and Suresh, P. (2020) 'Mo doped TiO<sub>2</sub>: impact on oxygen vacancies, anatase phase stability and photocatalytic activity', Journal of Physics: Materials, doi: 10.1088/2515-7639/ab749c