Semiconducting metal oxide photonic crystal plasmonic photocatalysts

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dc.contributor.author Collins, Gillian
dc.contributor.author Lonergan, Alex
dc.contributor.author McNulty, David
dc.contributor.author Glynn, Colm
dc.contributor.author Buckley, Darragh
dc.contributor.author Changyu, Hu
dc.contributor.author O'Dwyer, Colm
dc.date.accessioned 2020-05-11T15:52:32Z
dc.date.available 2020-05-11T15:52:32Z
dc.date.issued 2020-02-24
dc.identifier.citation Collins, G., Lonergan, A., McNulty, D., Glynn, C., Buckley, D., Hu, C. and O'Dwyer, C. (2020) 'Semiconducting Metal Oxide Photonic Crystal Plasmonic Photocatalysts'. Advanced Materials Interfaces, 7(8), 1901805 (11 pp). doi: 10.1002/admi.201901805 en
dc.identifier.volume 7 en
dc.identifier.issued 8 en
dc.identifier.startpage 1 en
dc.identifier.endpage 11 en
dc.identifier.uri http://hdl.handle.net/10468/9909
dc.identifier.doi 10.1002/admi.201901805 en
dc.description.abstract Plasmonic photocatalysis has facilitated rapid progress in enhancing photocatalytic efficiency under visible light irradiation. Poor visible‐light‐responsive photocatalytic materials and low photocatalytic efficiency remain major challenges. Plasmonic metal–semiconductor heterostructures where both the metal and semiconductor are photosensitive are promising for light harvesting catalysis, as both components can absorb solar light. Efficiency of photon capture can be further improved by structuring the catalyst as a photonic crystal. Here, the synthesis of photonic crystal plasmonic photocatalyst materials using Au nanoparticle‐functionalized inverse opal (IO) photonic crystals is reported. A catalyst prepared using a visible‐light‐responsive semiconductor (V2O5) displayed over an order of magnitude increase in reaction rate under green light excitation (λ = 532 nm) compared to no illumination. The superior performance of Au‐V2O5 IO is attributed to spectral overlap of the electronic bandgap, localized surface plasmon resonance, and incident light source. For the Au‐TiO2 catalyst, despite coupling of the LSPR and excitation source at λ = 532 nm, this is not as effective in enhancing photocatalytic activity compared to carrying out the reaction under broadband visible light, which is attributed to improved photon adsorption in the visible by the presence of a photonic bandgap, and exploiting slow light in the photonic crystal to enhance photon absorption to create this synergistic type of photocatalyst. en
dc.description.sponsorship Irish Research Council (Grant Numbers: GOIPG/2016/946, GOIPG/2014/206, IRCLA/2019/118) Science Foundation Ireland. Grant Numbers: 14/IA/2581, 15/TIDA/2893 en
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher Wiley en
dc.relation.uri https://onlinelibrary.wiley.com/doi/abs/10.1002/admi.201901805
dc.rights © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the peer reviewed version of the following article: Collins, G. et al 'Semiconducting Metal Oxide Photonic Crystal Plasmonic Photocatalysts', Adv. Mater. Interfaces 2020, 7, 1901805, which has been published in final form at https://doi.org/10.1002/admi.201901805. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. en
dc.subject Catalyst en
dc.subject Nitrophenol reduction en
dc.subject Photocatalysis en
dc.subject Photonic crystal en
dc.subject Plasmonic nanoparticles en
dc.title Semiconducting metal oxide photonic crystal plasmonic photocatalysts en
dc.type Article (peer-reviewed) en
dc.internal.authorcontactother Colm O'Dwyer, Chemistry, University College Cork, Cork, Ireland. +353-21-490-3000 Email: c.odwyer@ucc.ie en
dc.internal.availability Full text available en
dc.check.info Access to this article is restricted until 12 months after publication by request of the publisher. en
dc.check.date 2021-02-24
dc.date.updated 2020-05-11T11:44:37Z
dc.description.version Accepted Version en
dc.internal.rssid 513902422
dc.contributor.funder Irish Research Council en
dc.contributor.funder Science Foundation Ireland en
dc.description.status Peer reviewed en
dc.identifier.journaltitle Advanced Materials Interfaces en
dc.internal.copyrightchecked Yes
dc.internal.licenseacceptance Yes en
dc.internal.IRISemailaddress c.odwyer@ucc.ie en
dc.internal.IRISemailaddress g.collins@ucc.ie en
dc.identifier.articleid 1901805 en
dc.relation.project info:eu-repo/grantAgreement/SFI/SFI Investigator Programme/14/IA/2581/IE/Diffractive optics and photonic probes for efficient mouldable 3D printed battery skin materials for portable electronic devices/ en
dc.relation.project info:eu-repo/grantAgreement/SFI/SFI Technology and Innovation Development Award (TIDA)/15/TIDA/2893/IE/Advanced Battery Materials for High Volumetric Energy Density Li-ion Batteries for Remote Off-Grid Power/ en


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