Direct evidence of Fe2+ - Fe3+ charge ordering in the ferrimagnetic hematite-ilmenite Fe1.35Ti0.65O3−δ thin films

Thumbnail Image
3632.pdf(1.18 MB)
Published Version
Bocher, L.
Popova, Elena
Nolan, Michael
Gloter, Alexandre
Chikoidze, Ekaterina
March, K.
Warot-Fonrose, B.
Berini, B.
Stephan, Odile
Keller, Niels
Journal Title
Journal ISSN
Volume Title
American Physical Society
Research Projects
Organizational Units
Journal Issue
In this Letter we highlight direct experimental evidence of Fe2+-Fe3+ charge ordering at room temperature in hematite-ilmenite Fe1.35Ti0.65O3-delta epitaxial thin films grown by pulsed laser deposition, using aberration-corrected scanning transmission electron microscopy coupled to high-resolution energy electron-loss spectroscopy. These advanced spectromicroscopy techniques demonstrate a strong modulation of the Fe2+ valence state along the c axis. Density functional theory calculations provide crucial information on the key role of oxygen vacancies in the observed charge distributions. Their presence at significant levels leads to the localization of extra electrons onto reduced Fe2+ sites, while Ti remains solely +4. The magnetic and transport properties of these films are reviewed in the light of the present results regarding their ferrimagnetic character correlated with the Fe2+ modulation and their semi-conducting behavior interpreted by an Efros-Shklovskii variable-range hopping conduction regime via Fe2+ and Fe3+ centers. The experimental evidence of only one type of mixed valence state, i.e., Fe2+ and Fe3+, in the Fe2-xTixO3-delta system will thus help to interpret further the origin of its geomagnetic properties and to illuminate fundamental issues regarding its spintronic potential.
Solid solution series , Weak ferromagnetism , Electrical properties , Electronic structure , Magnetic properties , Crystal structure , High temperature , Fetio3 , Interface , System
Bocher, L., Popova, E., Nolan, M., Gloter, A., Chikoidze, E., March, K., Warot-Fonrose, B., Berini, B., Stéphan, O., Keller, N. and Dumont, Y. (2013) ‘Direct evidence of Fe2+ - Fe3+ charge ordering in the ferrimagnetic hematite-ilmenite Fe1.35Ti0.65O3−δ thin films’, Physical Review Letters, 111(16), 167202 (6pp). doi: 10.1103/PhysRevLett.111.167202
© 2013, American Physical Society