• Regioselective thermal [3+2]-dipolar cycloadditions of α-diazoacetates with α-sulfenyl/sulfinyl/sulfonyl-β-chloroacrylamide derivatives to form densely functionalised pyrazoles 

  Flynn, Aaran J.; Ford, Alan; Khandavilli, Udaya Bhaskara Rao; Lawrence, Simon E.; Maguire, Anita R. (Wiley, 2019-05-16)

  Highly regioselective synthetic methodology leading to densely functionalised C(3), C(4) and C(5) substituted pyrazoles 10a–q, 14a‐i and 16a–g via thermal [3+2]‐dipolar cycloaddition, of α‐diazoacetates and α‐thio‐β‐chlo ...
• Stepwise dissolution and composition determination of samples of multiple crystals using a dissolution medium containing aqueous alcohol and fluorocarbon phases 

  Moynihan, Humphrey A.; Armstrong, Declan (Royal Society of Chemistry, 2019-07)

  Crystallisations are widely used in pharmaceutical and fine chemical manufacturing to control impurity levels, however crystallisations do not always reduce impurities to acceptable levels. Information on the location and ...
• Investigating the mechanical properties of GeSn nanowires. 

  Kosmaca, Jelena; Meija, Raimonds; Antsov, Mikk; Kunakova, Gunta; Sonders, Raitis; Iatsunskyi, Igor; Coy, Emerson; Doherty, Jessica; Biswas, Subhajit; Holmes, Justin D.; Erts, Donats (Royal Society of Chemistry (RSC), 2019-07-10)

  Germanium tin (GeSn) has been proposed as a promising material for electronic and optical applications due to the formation of a direct band-gap at a Sn content >7 at%. Furthermore, the ability to manipulate the properties ...
• Resonance assisted jump-in voltage reduction for electrostatically actuated nanobeam-based gateless NEM switches. 

  Meija, Raimonds; Livshits, Alexander I.; Kosmaca, Jelena; Jasulaneca, Liga; Andzane, Jana; Biswas, Subhajit; Holmes, Justin D.; Erts, Donats (IOP Publishing, 2019-07-08)

  Electrostatically actuated nanobeam-based electromechanical switches have shown promise for versatile novel applications, such as low power devices. However, their widespread use is restricted due to poor reliability ...
• Mechanistic study of in situ generation and use of methanesulfonyl azide as a diazo transfer reagent with real-time monitoring by FlowNMR 

  Lynch, Denis; O'Mahony, Rosella M.; McCarthy, Daniel G.; Bateman, Lorraine M.; Collins, Stuart G.; Maguire, Anita R. (Wiley, 2019-05-07)

  The mechanistic pathway by which the hazardous diazo transfer reagent methanesulfonyl azide can be formed in situ, from methanesulfonyl chloride and aqueous sodium azide, has been investigated using real-time reaction ...

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