1,3-Dipolar cycloadditions of 2-thio-3-chloroacrylamides with diazoalkanes

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dc.contributor.authorKissane, Marie
dc.contributor.authorLawrence, Simon E.
dc.contributor.authorMaguire, Anita R.
dc.contributor.funderIrish Research Council for Science Engineering and Technologyen
dc.date.accessioned2012-05-29T15:26:42Z
dc.date.available2012-05-29T15:26:42Z
dc.date.copyright2010-04-23
dc.date.issued2010-06-21
dc.description.abstract2-Thio-3-chloroacrylamides undergo 1,3-dipolar cycloadditions with diazoalkanes leading to a series of novel pyrazolines and pyrazoles. The mechanistic and synthetic features of the cycloadditions to the 2-thio-3-chloroacrylamides at both the sulfide and sulfoxide levels of oxidation are rationalised on the basis of the nature of the substituents.en
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationKISSANE, M., LAWRENCE, S. E. & MAGUIRE, A. R. 2010. 1,3-Dipolar cycloadditions of 2-thio-3-chloroacrylamides with diazoalkanes. Organic & Biomolecular Chemistry, 8, 2735-2748. DOI: 10.1039/C002479Aen
dc.identifier.doi10.1039/C002479A
dc.identifier.endpage2748en
dc.identifier.issn1477-0520
dc.identifier.issued12en
dc.identifier.journaltitleOrganic and Biomolecular Chemistryen
dc.identifier.startpage2735en
dc.identifier.urihttps://hdl.handle.net/10468/596
dc.identifier.volume8en
dc.language.isoenen
dc.publisherRSC Publishingen
dc.relation.urihttp://pubs.rsc.org/en/content/articlelanding/2010/ob/c002479a
dc.relation.urihttp://www.rsc.org/suppdata/ob/c0/c002479a/c002479a.txt
dc.relation.urihttp://www.rsc.org/suppdata/ob/c0/c002479a/c002479a.pdf
dc.rights©2010, The Authors. Exclusive licence to publish RSC Publishing.en
dc.subject2-Thio-3-chloroacrylamidesen
dc.subject1,3-dipolar cycloadditionsen
dc.subjectPyrazolinesen
dc.subjectSulfideen
dc.subjectSulfoxideen
dc.subjectDiazoalkanesen
dc.subjectPhenyldiazomethaneen
dc.subjectCycloadditionsen
dc.subject.lcshOrganic compounds--Synthesisen
dc.title1,3-Dipolar cycloadditions of 2-thio-3-chloroacrylamides with diazoalkanesen
dc.typeArticle (peer-reviewed)en
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