Ultra-fast cycling of nanoscale thin-film LiCoO2 electrodes in aqueous electrolytes

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dc.check.date2019-08-03
dc.check.infoAccess to this article is restricted until 12 months after publication by request of the publisher.en
dc.contributor.authorClancy, Tomás M.
dc.contributor.authorRohan, James F.
dc.contributor.funderScience Foundation Irelanden
dc.contributor.funderEuropean Regional Development Funden
dc.date.accessioned2018-09-21T10:41:29Z
dc.date.available2018-09-21T10:41:29Z
dc.date.issued2018-08-03
dc.date.updated2018-09-14T08:25:47Z
dc.description.abstractAdditive‐free nanoscale LiCoO2 thin‐films deposited on Si substrates using DC sputtering show exceptional electrochemical performance due to the unique kinetics of the nanoscale thin‐film in aqueous environment. At extremely high scan rates and galvanostatic current densities of up to 100 mV s−1 and 200 C respectively, a capacity retention equivalent to 97 mAh g−1 (4.8 μAh cm−2, 48.3 μAh cm−2 μm−1) is obtained. A significant contribution of non‐diffusion controlled kinetics in a LiCoO2 electrode is shown.en
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationClancy, T. M. and Rohan, J. F. (2018) 'Ultra-fast cycling of nanoscale thin-film LiCoO2 electrodes in aqueous electrolytes', ChemElectroChem. doi: 10.1002/celc.201800822en
dc.identifier.doi10.1002/celc.201800822
dc.identifier.issn2196-0216
dc.identifier.journaltitleChemElectroChemen
dc.identifier.urihttps://hdl.handle.net/10468/6863
dc.language.isoenen
dc.publisherJohn Wiley & Sons, Inc.en
dc.relation.projectinfo:eu-repo/grantAgreement/SFI/SFI Investigator Programme/12/IP/1722/IE/Nanomaterials design and fabrication for Energy Storage/en
dc.relation.projectinfo:eu-repo/grantAgreement/SFI/SFI Research Centres/13/RC/2077/IE/CONNECT: The Centre for Future Networks & Communications/en
dc.rights© 2018, John Wiley & Sons Inc. This is the peer reviewed version of the following article: Clancy, T. M. and Rohan, J. F. (2018) 'Ultra-fast cycling of nanoscale thin-film LiCoO2 electrodes in aqueous electrolytes', ChemElectroChem. doi: 10.1002/celc.201800822, which has been published in final form at https://doi.org/10.1002/celc.201800822. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.en
dc.subjectAqueous electrolyteen
dc.subjectCathodeen
dc.subjectIntercalationsen
dc.subjectLiCoO2en
dc.subjectMaterials scienceen
dc.titleUltra-fast cycling of nanoscale thin-film LiCoO2 electrodes in aqueous electrolytesen
dc.typeArticle (peer-reviewed)en
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