Isotropic and anisotropic collision-induced Raman scattering by monoatomic gas mixtures: Ne-Ar

dc.contributor.authorDixneuf, Sophie
dc.contributor.authorChrysos, M.
dc.contributor.authorRachet, F.
dc.date.accessioned2017-08-25T10:08:52Z
dc.date.available2017-08-25T10:08:52Z
dc.date.issued2009
dc.description.abstractWe report the long-overdue collision-induced Raman scattering spectrum by a pair of unlike rare gas atoms. Absolute-unit scattering intensities, both isotropic and anisotropic, are given for Ne-Ar, along with the depolarization ratio for this system, recorded by a gaseous room-temperature mixture over a wide range of frequency shift. We make a critical comparison with spectra computed quantum-mechanically on the basis of modern pair-polarizability representations for Ne-Ar, of either ab initio or density functional theory methods. We report a value for the Kerr second virial coefficient, deduced from our measurements. Our data are especially intended to add to the vital yet hitherto incomplete knowledge of the role of collision-induced processes in atmospheric environments.en
dc.description.statusPeer revieweden
dc.description.versionPublished Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.articleid22703
dc.identifier.citationDixneuf, S., Chrysos, M. and Rachet, F. (2009) 'Isotropic and anisotropic collision-induced Raman scattering by monoatomic gas mixtures: Ne-Ar', Physical Review A, 80(2), 022703. (8pp). doi: 10.1103/PhysRevA.80.022703en
dc.identifier.doi10.1103/PhysRevA.80.022703
dc.identifier.issn1050-2947
dc.identifier.issn1094-1622
dc.identifier.issued2
dc.identifier.journaltitlePhysical Review Aen
dc.identifier.urihttps://hdl.handle.net/10468/4533
dc.identifier.volume80
dc.language.isoenen
dc.publisherAmerican Physical Societyen
dc.relation.urihttps://journals.aps.org/pra/abstract/10.1103/PhysRevA.80.022703
dc.rights© 2009, American Physical Societyen
dc.subjectInduced light scatteringen
dc.subjectAb initio calculationen
dc.subjectCorrelated molecular calculationsen
dc.subject2nd virial coefficientsen
dc.subjectElectric propertiesen
dc.subjectRare gasesen
dc.subjectArgonen
dc.titleIsotropic and anisotropic collision-induced Raman scattering by monoatomic gas mixtures: Ne-Aren
dc.typeArticle (peer-reviewed)en
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