Synthetic routes for the preparation of ordered vanadium oxide inverted opal electrodes for Li-ion batteries.

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dc.contributor.authorArmstrong, Eileen
dc.contributor.authorKhunshin, Worawut
dc.contributor.authorSotomayor Torres, Clivia M.
dc.contributor.authorOsiak, Michal J.
dc.contributor.authorO'Dwyer, Colm
dc.contributor.funderIrish Research Councilen
dc.contributor.funderMinisterio de Economía y Competitividaden
dc.contributor.funderScience Foundation Irelanden
dc.contributor.funderUniversity College Corken
dc.date.accessioned2018-05-22T10:31:17Z
dc.date.available2018-05-22T10:31:17Z
dc.date.issued2014-04
dc.date.updated2018-05-16T00:40:48Z
dc.description.abstractSynthetic routes for the formation of opal assemblies as templates for the inverted opal vanadium oxide electrodes are presented. A method for the formation of monolayer opal templates on gold substrates is discussed and the formation of multilayer opal templates on conductive substrates by electrophoretic deposition is also described, with order defined by angle resolved light scattering measurements. Inverted opals are formed from a diluted solution of IPA and vanadium alkoxide precursor, infiltrated into the templates by several methods. The effect of different heat treatments and method of polymer template removal on the resulting inverse opal morphology and structure is investigated.en
dc.description.sponsorshipIrish Research Council ((awards RS/2010/2920 and RS/2010/2170), Irish Research Council New Foundations Award); Ministerio de Economía y Competitividad (Spanish National I+D Plan projects TAPHOR (MAT-2012-31392) and CONSOLIDER nanoTHERM (CSD2010-00044)); University College Cork ( UCC Strategic Research Fund)en
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationArmstrong, E., Khunsin, W., Sotomayor Torres, C. M., Osiak, M. and O'Dwyer, C. (2014) 'Synthetic Routes for the Preparation of Ordered Vanadium Oxide Inverted Opal Electrodes for Li-Ion Batteries', ECS Transactions, 58(25), pp. 7-14. doi: 10.1149/05825.0007ecsten
dc.identifier.doi10.1149/05825.0007ecst
dc.identifier.endpage14en
dc.identifier.issn1938-5862
dc.identifier.issn1938-6737
dc.identifier.journaltitleECS Transactionsen
dc.identifier.startpage7en
dc.identifier.urihttps://hdl.handle.net/10468/6169
dc.identifier.volume58en
dc.language.isoenen
dc.publisherElectrochemical Societyen
dc.relation.projectinfo:eu-repo/grantAgreement/SFI/SFI Short Term Travel Fellowship (STTF)/07/SK/B1232a - STTF 11/IE/Optical Probing of Phase Changes in Inverse opal Photonic Crystal Li-on Battery Electrodes/en
dc.relation.urihttp://ecst.ecsdl.org/content/58/25/7.abstract
dc.rights© 2014 ECS - The Electrochemical Societyen
dc.subjectElectrodesen
dc.subjectDepositionen
dc.subjectElectrophoresisen
dc.subjectLithium batteriesen
dc.subjectOxidesen
dc.subjectSilicate mineralsen
dc.subjectAlkoxide precursoren
dc.subjectAngle-resolved light scatteringen
dc.subjectConductive substratesen
dc.subjectDiluted solutionsen
dc.subjectElectrophoretic depositionsen
dc.subjectLi-ion batteriesen
dc.subjectMorphology and structuresen
dc.subjectPolymer templatesen
dc.titleSynthetic routes for the preparation of ordered vanadium oxide inverted opal electrodes for Li-ion batteries.en
dc.typeArticle (peer-reviewed)en
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