Recent advances in manganese-catalysed C–H activation: scope and mechanism

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dc.contributor.authorMackey, Katrina
dc.contributor.authorMcGlacken, Gerard P.
dc.contributor.authorCano, Rafael
dc.contributor.funderScience Foundation Irelanden
dc.date.accessioned2019-03-04T12:08:18Z
dc.date.available2019-03-04T12:08:18Z
dc.date.issued2018
dc.date.updated2019-03-04T11:58:39Z
dc.description.abstractAs a synthetic methodology, C–H activation represents a complimentary protocol to traditional cross-couplings such as the Suzuki–Miyaura and Stille reactions, by avoiding the extra synthetic steps required to install activating groups. C–H activation also often avoids the production of waste associated with B, Sn, halide etc. Pd-catalysed transformations have been most prominent in the C–H activation realm. However, as a society we are over-reliant on transitional metals, cost is increasing, and the accessible supply is dwindling. One potential solution is to develop chemistry using Earth Abundant Metals (EAMs). Manganese (Mn), in particular, demonstrates great promise. Since the publication of an excellent review by Ackermann in 2016 (ACS Catal. 2016, 6, 3743–3652), there has been a flurry of reports on Mn-catalysed C–H activation. We report here an overview of approximately 30 new papers, which include a number of notable advances since April 2016.en
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationCano, R., Mackey, K. and McGlacken, G. P. (2018) 'Recent advances in manganese-catalysed C–H activation: scope and mechanism', Catalysis Science & Technology, 8(5), pp. 1251-1266. doi: 10.1039/C7CY02514Aen
dc.identifier.doi10.1039/C7CY02514A
dc.identifier.endpage1266en
dc.identifier.issn2044-4753
dc.identifier.issued5en
dc.identifier.journaltitleCatalysis Science & Technologyen
dc.identifier.startpage1251en
dc.identifier.urihttps://hdl.handle.net/10468/7560
dc.identifier.volume8en
dc.language.isoenen
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.projectinfo:eu-repo/grantAgreement/SFI/SFI Investigator Programme/12/IP/1315/IE/The Direct Arylation of Pyrones, Coumarins, Pyridones and Quinolones/en
dc.relation.projectinfo:eu-repo/grantAgreement/SFI/SFI Research Centres/12/RC/2275/IE/Synthesis and Solid State Pharmaceutical Centre (SSPC)/en
dc.relation.urihttps://pubs.rsc.org/en/content/articlelanding/2018/cy/c7cy02514a
dc.rights© The Royal Society of Chemistry 2018. This is the accepted version of an article published in Catalysis Science & Technology. The published version is available online at: http://dx.doi.org/10.1039/C7CY02514Aen
dc.subjectCritical raw materialsen
dc.subjectC-H activationen
dc.subjectEarth Abundant Metals (EAMs)en
dc.subjectManganese-based catalytic systems.en
dc.subjectSynthetic methodologyen
dc.titleRecent advances in manganese-catalysed C–H activation: scope and mechanismen
dc.typeArticle (peer-reviewed)en
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