Recent advances in manganese-catalysed C–H activation: scope and mechanism
dc.contributor.author | Mackey, Katrina | |
dc.contributor.author | McGlacken, Gerard P. | |
dc.contributor.author | Cano, Rafael | |
dc.contributor.funder | Science Foundation Ireland | en |
dc.date.accessioned | 2019-03-04T12:08:18Z | |
dc.date.available | 2019-03-04T12:08:18Z | |
dc.date.issued | 2018 | |
dc.date.updated | 2019-03-04T11:58:39Z | |
dc.description.abstract | As a synthetic methodology, C–H activation represents a complimentary protocol to traditional cross-couplings such as the Suzuki–Miyaura and Stille reactions, by avoiding the extra synthetic steps required to install activating groups. C–H activation also often avoids the production of waste associated with B, Sn, halide etc. Pd-catalysed transformations have been most prominent in the C–H activation realm. However, as a society we are over-reliant on transitional metals, cost is increasing, and the accessible supply is dwindling. One potential solution is to develop chemistry using Earth Abundant Metals (EAMs). Manganese (Mn), in particular, demonstrates great promise. Since the publication of an excellent review by Ackermann in 2016 (ACS Catal. 2016, 6, 3743–3652), there has been a flurry of reports on Mn-catalysed C–H activation. We report here an overview of approximately 30 new papers, which include a number of notable advances since April 2016. | en |
dc.description.status | Peer reviewed | en |
dc.description.version | Accepted Version | en |
dc.format.mimetype | application/pdf | en |
dc.identifier.citation | Cano, R., Mackey, K. and McGlacken, G. P. (2018) 'Recent advances in manganese-catalysed C–H activation: scope and mechanism', Catalysis Science & Technology, 8(5), pp. 1251-1266. doi: 10.1039/C7CY02514A | en |
dc.identifier.doi | 10.1039/C7CY02514A | |
dc.identifier.endpage | 1266 | en |
dc.identifier.issn | 2044-4753 | |
dc.identifier.issued | 5 | en |
dc.identifier.journaltitle | Catalysis Science & Technology | en |
dc.identifier.startpage | 1251 | en |
dc.identifier.uri | https://hdl.handle.net/10468/7560 | |
dc.identifier.volume | 8 | en |
dc.language.iso | en | en |
dc.publisher | Royal Society of Chemistry (RSC) | en |
dc.relation.project | info:eu-repo/grantAgreement/SFI/SFI Investigator Programme/12/IP/1315/IE/The Direct Arylation of Pyrones, Coumarins, Pyridones and Quinolones/ | en |
dc.relation.project | info:eu-repo/grantAgreement/SFI/SFI Research Centres/12/RC/2275/IE/Synthesis and Solid State Pharmaceutical Centre (SSPC)/ | en |
dc.relation.uri | https://pubs.rsc.org/en/content/articlelanding/2018/cy/c7cy02514a | |
dc.rights | © The Royal Society of Chemistry 2018. This is the accepted version of an article published in Catalysis Science & Technology. The published version is available online at: http://dx.doi.org/10.1039/C7CY02514A | en |
dc.subject | Critical raw materials | en |
dc.subject | C-H activation | en |
dc.subject | Earth Abundant Metals (EAMs) | en |
dc.subject | Manganese-based catalytic systems. | en |
dc.subject | Synthetic methodology | en |
dc.title | Recent advances in manganese-catalysed C–H activation: scope and mechanism | en |
dc.type | Article (peer-reviewed) | en |
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