Electronic structure evolution in dilute carbide Ge1-xCx alloys and implications for device applications
| dc.contributor.author | Broderick, Christopher A. | |
| dc.contributor.author | Dunne, Michael D. | |
| dc.contributor.author | Tanner, Daniel S. P. | |
| dc.contributor.author | O'Reilly, Eoin P. | |
| dc.contributor.funder | Science Foundation Ireland | en |
| dc.contributor.funder | National University of Ireland | en |
| dc.date.accessioned | 2020-01-14T10:11:00Z | |
| dc.date.available | 2020-01-14T10:11:00Z | |
| dc.date.issued | 2019-11-20 | |
| dc.date.updated | 2019-12-04T09:58:01Z | |
| dc.description.abstract | We present a theoretical analysis of electronic structure evolution in the highly-mismatched dilute carbide group-IV alloy Ge1−xCx. For ordered alloy supercells, we demonstrate that C incorporation strongly perturbs the conduction band (CB) structure by driving the hybridization of A1-symmetric linear combinations of Ge states lying close in energy to the CB edge. This leads, in the ultradilute limit, to the alloy CB edge being formed primarily of an A1-symmetric linear combination of the L-point CB edge states of the Ge host matrix semiconductor. Our calculations describe the emergence of a “quasidirect” alloy bandgap, which retains a significant admixture of indirect Ge L-point CB edge character. We then analyze the evolution of the electronic structure of realistic (large, disordered) Ge1−xCx alloy supercells for C compositions up to x=2%. We show that short-range alloy disorder introduces a distribution of localized states at energies below the Ge CB edge, with these states acquiring minimal direct (Γ) character. Our calculations demonstrate strong intrinsic inhomogeneous energy broadening of the CB edge Bloch character, driven by hybridization between Ge host matrix and C-related localized states. The trends identified by our calculations are markedly different to those expected based on a recently proposed interpretation of the CB structure based on the band anticrossing model. The implications of our findings for device applications are discussed. | en |
| dc.description.sponsorship | National University of Ireland (Post-Doctoral Fellowship in the Sciences) | en |
| dc.description.status | Peer reviewed | en |
| dc.description.version | Published Version | en |
| dc.format.mimetype | application/pdf | en |
| dc.identifier.articleid | 195702 | en |
| dc.identifier.citation | Broderick, C. A., Dunne, M. D., Tanner, D. S. P. and O'Reilly, E. P. (2019) 'Electronic structure evolution in dilute carbide Ge1-xCx alloys and implications for device applications', Journal of Applied Physics, 126(19), 195702 (15pp). doi: 10.1063/1.5111976 | en |
| dc.identifier.doi | 10.1063/1.5111976 | en |
| dc.identifier.eissn | 1089-7550 | |
| dc.identifier.endpage | 15 | en |
| dc.identifier.issn | 0021-8979 | |
| dc.identifier.issued | 19 | en |
| dc.identifier.journaltitle | Journal of Applied Physics | en |
| dc.identifier.startpage | 1 | en |
| dc.identifier.uri | https://hdl.handle.net/10468/9498 | |
| dc.identifier.volume | 126 | en |
| dc.language.iso | en | en |
| dc.publisher | AIP Publishing | en |
| dc.relation.project | info:eu-repo/grantAgreement/SFI/SFI Investigator Programme/15/IA/3082/IE/Multiscale Simulation and Analysis of emerging Group IV and III-V Semiconductor Materials and Devices/ | en |
| dc.relation.uri | https://aip.scitation.org/doi/abs/10.1063/1.5111976 | |
| dc.rights | © 2019, the Authors. Published under license by AIP Publishing. This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared Broderick, C. A., Dunne, M. D., Tanner, D. S. P. and O'Reilly, E. P. (2019) 'Electronic structure evolution in dilute carbide Ge1-xCx alloys and implications for device applications', Journal of Applied Physics, 126(19), 195702 (15pp), doi: 10.1063/1.5111976 and may be found at https://doi.org/10.1063/1.5111976 | en |
| dc.subject | Electronic structure evolution | en |
| dc.subject | C incorporation | en |
| dc.subject | Conduction band | en |
| dc.subject | Quasidirect | en |
| dc.subject | Alloy bandgap | en |
| dc.subject | Ge1−xCx | en |
| dc.title | Electronic structure evolution in dilute carbide Ge1-xCx alloys and implications for device applications | en |
| dc.type | Article (peer-reviewed) | en |
