Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds

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dc.contributor.authorSlattery, Catherine N.
dc.contributor.authorClarke, Leslie-Ann
dc.contributor.authorO'Neill, Shane T.
dc.contributor.authorRing, Aoife
dc.contributor.authorFord, Alan
dc.contributor.authorMaguire, Anita R.
dc.contributor.funderIrish Research Council for Science Engineering and Technologyen
dc.contributor.funderEli Lilly and Company, United Statesen
dc.date.accessioned2016-08-16T15:19:01Z
dc.date.available2016-08-16T15:19:01Z
dc.date.issued2012-01
dc.date.updated2013-01-08T12:15:19Z
dc.description.abstractSignificant enhancements in enantioselectivities and reaction efficiencies in asymmetric copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds in the presence of various group I salts are reported. For the first time in carbenoid chemistry, evidence for the critical role of the metal cation is described.en
dc.description.sponsorshipIrish Research Council for Science, Engineering and Technology (Programme for Research in Third Level Institutions Cycle 4); Eli Lilly and Company, United Statesen
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.articleidD62911ST
dc.identifier.citationSlattery, C. N., Clarke, L. A., O'Neill, S., Ring, A., Ford, A. and Maguire, A. R. (2012) 'Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds', Synlett, 23(5), pp. 765-767. DOI: 10.1055/s-0031-1290598en
dc.identifier.doi10.1055/s-0031-1290598
dc.identifier.endpage767en
dc.identifier.issn0936-5214
dc.identifier.issn1437-2096
dc.identifier.issued5en
dc.identifier.journaltitleSynletten
dc.identifier.startpage765en
dc.identifier.urihttps://hdl.handle.net/10468/2997
dc.identifier.volume23en
dc.language.isoenen
dc.publisherGeorg Thieme Verlagen
dc.rights© Georg Thieme Verlag Stuttgart · New Yorken
dc.subjectC-H insertionen
dc.subjectBuchner reactionen
dc.subjectDiazocarbonylen
dc.subjectCopper catalysisen
dc.subjectBis(oxazoline) ligandsen
dc.subjectCarbene insertionen
dc.subjectBondsen
dc.subjectComplexesen
dc.titleInvestigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compoundsen
dc.typeArticle (peer-reviewed)en
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