Functionalization of germanium nanowires

dc.contributor.authorCollins, Gillian
dc.contributor.authorFleming, Peter G.
dc.contributor.authorO'Dwyer, Colm
dc.contributor.authorMorris, Michael A.
dc.contributor.authorHolmes, Justin D.
dc.contributor.funderIrish Research Council for Science, Engineering and Technologyen
dc.contributor.funderScience Foundation Irelanden
dc.contributor.funderHigher Education Authorityen
dc.date.accessioned2013-02-26T12:54:30Z
dc.date.available2013-02-26T12:54:30Z
dc.date.copyright2011
dc.date.issued2011-01
dc.date.updated2012-11-30T12:20:26Z
dc.description.abstractHalogen-termination and organic functionalization of germanium (Ge) nanowires is described. X-ray photoelectron spectroscopy (XPS), X-ray photoemission electron spectroscopy (XPEEM), infrared spectroscopy (IR) and transmission electron spectroscopy (TEM) were used to characterize the modified nanowire surfaces. The stability of alkyl and alkanethiol monolayers formed on Cl, Br and I-terminated surfaces are compared. The direct covalent attachment of aryl ligands onto H-Ge nanowires can be achieved by the decomposition of arenediazonium salts in acetonitrile solutions. The influence of the ring substituent on the thickness and uniformity of the functionalization layer was investigated.en
dc.description.sponsorshipIrish Research Council for Science and Engineering Technology; Higher Education Authority (under the framework of the INSPIRE programme, funded by the Irish Government's Programme for Research in Third Level Institutions, Cycle 4, National Development Plan 2007-2013)en
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationCollins, G., Fleming, P., O'Dwyer, C., Morris, M. A., and Holmes, J. D. (2011) 'Functionalization of Germanium Nanowires', ECS Transactions, 35(8), pp. 89-99; doi:10.1149/1.3567740en
dc.identifier.doi10.1149/1.3567740
dc.identifier.endpage99en
dc.identifier.issn1938-5862
dc.identifier.issn1938-6737
dc.identifier.issued8en
dc.identifier.journaltitleECS Transactionsen
dc.identifier.startpage89en
dc.identifier.urihttps://hdl.handle.net/10468/991
dc.identifier.volume35en
dc.language.isoenen
dc.publisherThe Electrochemical Societyen
dc.relation.projectinfo:eu-repo/grantAgreement/SFI/SFI Centre for Science Engineering and Technology (CSET)/08/CE/I1432/IE/CSET CRANN: 2nd Term funding/
dc.relation.urihttp://ecst.ecsdl.org/content/35/8/89
dc.rights© The Electrochemical Society, Inc. 2011. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in Collins, G., Fleming, P., O'Dwyer, C., Morris, M. A., Holmes, J. D. (2011) 'Functionalization of Germanium Nanowires'. ECS Transactions, 35(8), pp. 89-99; doi:10.1149/1.3567740en
dc.subjectGermaniumen
dc.subjectNanowiresen
dc.subjectX-ray photoelectron spectroscopy (XPS)en
dc.subjectX-ray photoemission electron spectroscopy (XPEEM)en
dc.subjectInfrared spectroscopy (IR)en
dc.subjectTransmission electron spectroscopy (TEM)en
dc.titleFunctionalization of germanium nanowiresen
dc.typeArticle (peer-reviewed)en
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