Effects of commercial no-clean flux on reliability of fine pitch flip-chip package with solder bumps and copper pillars

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Date
2022-07-15
Authors
Wakeel, Saif
Haseeb, A. S. M. A.
Hoon, Khoo Ly
Amalina, M. A.
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Institute of Electrical and Electronics Engineers (IEEE)
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Abstract
In this work, two commercial no clean fluxes, namely, extremely low residue no-clean flux (NCF) (NC-1) and ordinary NCF (NC-2), were used for the preparation of a fine pitch flip-chip package with a 7.6×7.6 mm 2 Si die on a 17×17 mm 2 organic substrate. One water-soluble (WS) flux was also used for comparison. Moisture sensitivity of the package was evaluated using JESD22-A113D (30 °C/60% relative humidity (RH), 192 h, 3× reflow at 260 °C). Thermal cycling tests were performed following JESD22-A104D (−65 °C to 150 °C). The high-temperature storage life (HTSL) of the packages was investigated using JESD22-A103C (175 °C). Underfill delamination or voids in the package were investigated by confocal scanning acoustic microscopy (C-SAM). Failure characteristics of the packages were also studied using scanning electron microscopy (SEM). After moisture sensitivity level (MSL) test, vehicles prepared by NC-1 and NC-2 showed failure. SEM images revealed severe delamination between underfill and solder mask in the presence of amine/amide and carboxylic acid-based NCF residue. Solder bump crack were found at < 500 cycles for samples prepared with NC-1 which contains tertiary amine and long carbon chain (C8:C10:C12) carboxylic acid-based. However, failure occurred at < 1500 cycles for NC-2 containing secondary amide and shorter carbon chain length (C3) carboxylic acid. Samples prepared using WS did not show any failure for up to 2000 cycles. Thus, NCF-treated assemblies performed poorly in moisture sensitivity and temperature cycling tests.
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Keywords
Copper , Delamination , Electronic packaging thermal management , Flip-chip devices , High temperature storage life , Moisture , Moisture sensitivity , No-clean flux , Reliability , Reliability analysis , Sensitivity , Thermal cycling , Underfill delamination
Citation
Wakeel, S., Haseeb, A. S. M. A., Hoon, K. L. and Amalina, M. A. (2022) 'Effects of commercial no-clean flux on reliability of fine pitch flip-chip package with solder bumps and copper pillars', IEEE Transactions on Components Packaging and Manufacturing Technology, 12(8), pp. 1386-1394. doi: 10.1109/TCPMT.2022.3191604
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