Citation:HAYES, J. A., ECCLES, K. S., COLES, S. J., LAWRENCE, S. E. & MOYNIHAN, H. A. 2014. Supramolecular stacking motifs in the solid state of amide and triazole derivatives of cellobiose. Carbohydrate Research, 388, 67-72. http://dx.doi.org/10.1016/j.carres.2014.02.011
1-Acetamido-1-deoxy-(4-O-β-d-glucopyranosyl-β-d-glucopyranose) (5) and 1-deoxy-1-(4-phenyl-1,2,3-triazolyl)-(4-O-β-d-glucopyranosyl-β-d-glucopyranose) (7) were synthesised from 1-azido-1-deoxy-(4-O-β-d-glucopyranosyl-β-d-glucopyranose) (2) and crystallised as dihydrates. Crystal structural analysis of 5·2H2O displayed an acetamide C(4) chain and stacked cellobiose residues. The structure of 7·2H2O featured π–π stacking and stacking of the cellobiose residues
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