Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds

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Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds

Slattery, Catherine N.; Clarke, Leslie-Ann; O'Neill, Shane T.; Ring, Aoife; Ford, Alan; Maguire, Anita R.
Date: 2012-01
Copyright: © Georg Thieme Verlag Stuttgart · New York
Citation: Slattery, C. N., Clarke, L. A., O'Neill, S., Ring, A., Ford, A. and Maguire, A. R. (2012) 'Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds', Synlett, 23(5), pp. 765-767. DOI: 10.1055/s-0031-1290598
Published Version: 10.1055/s-0031-1290598

Abstract:

Significant enhancements in enantioselectivities and reaction efficiencies in asymmetric copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds in the presence of various group I salts are reported. For the first time in carbenoid chemistry, evidence for the critical role of the metal cation is described.

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