Catalytic asymmetric C-H insertion reactions of α-diazocarbonyl compounds

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dc.contributor.author Slattery, Catherine N.
dc.contributor.author Ford, Alan
dc.contributor.author Maguire, Anita R.
dc.date.accessioned 2012-05-14T15:14:14Z
dc.date.available 2012-05-14T15:14:14Z
dc.date.copyright 2010-08-21
dc.date.issued 2010-08-21
dc.identifier.citation Slattery, C. N., Ford, A. and Maguire, A. R. (2010) 'Catalytic asymmetric C–H insertion reactions of α-diazocarbonyl compounds', Tetrahedron, 66(34), pp. 6681-6705. doi: 10.1016/j.tet.2010.05.073 en
dc.identifier.volume 66 en
dc.identifier.issued 34 en
dc.identifier.startpage 6681 en
dc.identifier.endpage 6705 en
dc.identifier.issn 0040-4020
dc.identifier.uri http://hdl.handle.net/10468/585
dc.identifier.doi 10.1016/j.tet.2010.05.073
dc.description.abstract The purpose of this review is to provide an overview of the development of asymmetric catalysts for C-H insertion reactions over the past two decades, focusing on the application of these catalysts in the decomposition of α-diazocarbonyl compounds. Given the rapid pace of development in the field of enantioselective C-H insertion chemistry, an up-to-date review of this type is warranted. While recent reviews22,23 have dissected their content into intramolecular and intermolecular processes, this article is differentiated in extending this division to include classification of C-H insertion reactions according to product type. Thus, catalytic methods for the asymmetric synthesis of carbocyclic compounds, oxygen-containing heterocycles, nitrogen-containing heterocycles and sulfur-containing heterocycles are readily identifiable. Due to the diversity of compounds resulting from intermolecular C-H insertion processes, classification of reactions by product type was not attempted in this section of the review. en
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher Elsevier en
dc.relation.ispartofseries Tetrahedron Report;Number 916
dc.rights Copyright © 2010 Elsevier Ltd. All rights reserved. NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron, [Vol. 66, Iissue 34, (21/08/2010)] doi: 10.1016/j.tet.2010.05.073 en
dc.subject Asymmetric catalysts en
dc.subject C-H insertion en
dc.subject Decomposition en
dc.subject α-diazocarbonyl en
dc.subject Enantioselective en
dc.subject.lcsh Metal catalysts en
dc.subject.lcsh Copper catalysts en
dc.title Catalytic asymmetric C-H insertion reactions of α-diazocarbonyl compounds en
dc.type Article (peer-reviewed) en
dc.internal.authorurl http://publish.ucc.ie/researchprofiles/V001/amaguire en
dc.internal.authorcontactother Department of Chemistry & School of Pharmacy, Analytical and Biological Chemistry Research Facility, University College Cork, Ireland. Tel.: +353 (0)21 4901694 en
dc.internal.availability Full text available en
dc.description.version Accepted Version en
dc.internal.rssid 21057281
dc.contributor.funder Irish Research Council for Science Engineering and Technology en
dc.contributor.funder Eli Lilly and Company, United States en
dc.description.status Peer reviewed en
dc.identifier.journaltitle Tetrahedron en
dc.internal.copyrightchecked Added text to "Rights" field as required by publisher. No requirement for copyright url link, or link to published version. en
dc.internal.IRISemailaddress a.maguire@ucc.ie en


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