Synthetic routes for the preparation of ordered vanadium oxide inverted opal electrodes for Li-ion batteries.

Armstrong, Eileen; Khunshin, Worawut; Sotomayor Torres, Clivia M.; Osiak, Michal J.; O'Dwyer, Colm

doi:10.1149/05825.0007ecst

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dc.contributor.author	Armstrong, Eileen
dc.contributor.author	Khunshin, Worawut
dc.contributor.author	Sotomayor Torres, Clivia M.
dc.contributor.author	Osiak, Michal J.
dc.contributor.author	O'Dwyer, Colm
dc.date.accessioned	2018-05-22T10:31:17Z
dc.date.available	2018-05-22T10:31:17Z
dc.date.issued	2014-04
dc.identifier.citation	Armstrong, E., Khunsin, W., Sotomayor Torres, C. M., Osiak, M. and O'Dwyer, C. (2014) 'Synthetic Routes for the Preparation of Ordered Vanadium Oxide Inverted Opal Electrodes for Li-Ion Batteries', ECS Transactions, 58(25), pp. 7-14. doi: 10.1149/05825.0007ecst	en
dc.identifier.volume	58	en
dc.identifier.startpage	7	en
dc.identifier.endpage	14	en
dc.identifier.issn	1938-5862
dc.identifier.issn	1938-6737
dc.identifier.uri	http://hdl.handle.net/10468/6169
dc.identifier.doi	10.1149/05825.0007ecst
dc.description.abstract	Synthetic routes for the formation of opal assemblies as templates for the inverted opal vanadium oxide electrodes are presented. A method for the formation of monolayer opal templates on gold substrates is discussed and the formation of multilayer opal templates on conductive substrates by electrophoretic deposition is also described, with order defined by angle resolved light scattering measurements. Inverted opals are formed from a diluted solution of IPA and vanadium alkoxide precursor, infiltrated into the templates by several methods. The effect of different heat treatments and method of polymer template removal on the resulting inverse opal morphology and structure is investigated.	en
dc.description.sponsorship	Irish Research Council ((awards RS/2010/2920 and RS/2010/2170), Irish Research Council New Foundations Award); Ministerio de Economía y Competitividad (Spanish National I+D Plan projects TAPHOR (MAT-2012-31392) and CONSOLIDER nanoTHERM (CSD2010-00044)); University College Cork ( UCC Strategic Research Fund)	en
dc.format.mimetype	application/pdf	en
dc.language.iso	en	en
dc.publisher	Electrochemical Society	en
dc.relation.uri	http://ecst.ecsdl.org/content/58/25/7.abstract
dc.rights	© 2014 ECS - The Electrochemical Society	en
dc.subject	Electrodes	en
dc.subject	Deposition	en
dc.subject	Electrophoresis	en
dc.subject	Lithium batteries	en
dc.subject	Oxides	en
dc.subject	Silicate minerals	en
dc.subject	Alkoxide precursor	en
dc.subject	Angle-resolved light scattering	en
dc.subject	Conductive substrates	en
dc.subject	Diluted solutions	en
dc.subject	Electrophoretic depositions	en
dc.subject	Li-ion batteries	en
dc.subject	Morphology and structures	en
dc.subject	Polymer templates	en
dc.title	Synthetic routes for the preparation of ordered vanadium oxide inverted opal electrodes for Li-ion batteries.	en
dc.type	Article (peer-reviewed)	en
dc.internal.authorcontactother	Colm O'Dwyer, Chemistry, University College Cork, Cork, Ireland. +353-21-490-3000 Email: c.odwyer@ucc.ie	en
dc.internal.availability	Full text available	en
dc.date.updated	2018-05-16T00:40:48Z
dc.description.version	Accepted Version	en
dc.internal.rssid	254294182
dc.contributor.funder	Irish Research Council	en
dc.contributor.funder	Ministerio de Economía y Competitividad	en
dc.contributor.funder	Science Foundation Ireland	en
dc.contributor.funder	University College Cork	en
dc.description.status	Peer reviewed	en
dc.identifier.journaltitle	ECS Transactions	en
dc.internal.copyrightchecked	Yes	en
dc.internal.licenseacceptance	Yes	en
dc.internal.IRISemailaddress	c.odwyer@ucc.ie	en
dc.relation.project	info:eu-repo/grantAgreement/SFI/SFI Short Term Travel Fellowship (STTF)/07/SK/B1232a - STTF 11/IE/Optical Probing of Phase Changes in Inverse opal Photonic Crystal Li-on Battery Electrodes/	en