Synthetic routes for the preparation of ordered vanadium oxide inverted opal electrodes for Li-ion batteries.

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dc.contributor.author Armstrong, Eileen
dc.contributor.author Khunshin, Worawut
dc.contributor.author Sotomayor Torres, Clivia M.
dc.contributor.author Osiak, Michal J.
dc.contributor.author O'Dwyer, Colm
dc.date.accessioned 2018-05-22T10:31:17Z
dc.date.available 2018-05-22T10:31:17Z
dc.date.issued 2014-04
dc.identifier.citation Armstrong, E., Khunsin, W., Sotomayor Torres, C. M., Osiak, M. and O'Dwyer, C. (2014) 'Synthetic Routes for the Preparation of Ordered Vanadium Oxide Inverted Opal Electrodes for Li-Ion Batteries', ECS Transactions, 58(25), pp. 7-14. doi: 10.1149/05825.0007ecst en
dc.identifier.volume 58 en
dc.identifier.startpage 7 en
dc.identifier.endpage 14 en
dc.identifier.issn 1938-5862
dc.identifier.issn 1938-6737
dc.identifier.uri http://hdl.handle.net/10468/6169
dc.identifier.doi 10.1149/05825.0007ecst
dc.description.abstract Synthetic routes for the formation of opal assemblies as templates for the inverted opal vanadium oxide electrodes are presented. A method for the formation of monolayer opal templates on gold substrates is discussed and the formation of multilayer opal templates on conductive substrates by electrophoretic deposition is also described, with order defined by angle resolved light scattering measurements. Inverted opals are formed from a diluted solution of IPA and vanadium alkoxide precursor, infiltrated into the templates by several methods. The effect of different heat treatments and method of polymer template removal on the resulting inverse opal morphology and structure is investigated. en
dc.description.sponsorship Irish Research Council ((awards RS/2010/2920 and RS/2010/2170), Irish Research Council New Foundations Award); Ministerio de Economía y Competitividad (Spanish National I+D Plan projects TAPHOR (MAT-2012-31392) and CONSOLIDER nanoTHERM (CSD2010-00044)); University College Cork ( UCC Strategic Research Fund) en
dc.format.mimetype application/pdf en
dc.language.iso en en
dc.publisher Electrochemical Society en
dc.relation.uri http://ecst.ecsdl.org/content/58/25/7.abstract
dc.rights © 2014 ECS - The Electrochemical Society en
dc.subject Electrodes en
dc.subject Deposition en
dc.subject Electrophoresis en
dc.subject Lithium batteries en
dc.subject Oxides en
dc.subject Silicate minerals en
dc.subject Alkoxide precursor en
dc.subject Angle-resolved light scattering en
dc.subject Conductive substrates en
dc.subject Diluted solutions en
dc.subject Electrophoretic depositions en
dc.subject Li-ion batteries en
dc.subject Morphology and structures en
dc.subject Polymer templates en
dc.title Synthetic routes for the preparation of ordered vanadium oxide inverted opal electrodes for Li-ion batteries. en
dc.type Article (peer-reviewed) en
dc.internal.authorcontactother Colm O'Dwyer, Chemistry, University College Cork, Cork, Ireland. +353-21-490-3000 Email: c.odwyer@ucc.ie en
dc.internal.availability Full text available en
dc.date.updated 2018-05-16T00:40:48Z
dc.description.version Accepted Version en
dc.internal.rssid 254294182
dc.contributor.funder Irish Research Council en
dc.contributor.funder Ministerio de Economía y Competitividad en
dc.contributor.funder Science Foundation Ireland en
dc.contributor.funder University College Cork en
dc.description.status Peer reviewed en
dc.identifier.journaltitle ECS Transactions en
dc.internal.copyrightchecked Yes en
dc.internal.licenseacceptance Yes en
dc.internal.IRISemailaddress c.odwyer@ucc.ie en
dc.relation.project info:eu-repo/grantAgreement/SFI/SFI Short Term Travel Fellowship (STTF)/07/SK/B1232a - STTF 11/IE/Optical Probing of Phase Changes in Inverse opal Photonic Crystal Li-on Battery Electrodes/ en


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