Ligand design for long-range magnetic order in metal-organic frameworks

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Date
2014-09-23
Authors
Tiana, Davide
Hendon, Christopher H.
Walsh, Aron
Journal Title
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Volume Title
Publisher
Royal Society of Chemistry (RSC)
Published Version
10.1039/c4cc06433j
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Abstract
We report a class of ligands that are candidates to construct metal-organic frameworks with long-range magnetic order between transition metal centres. Direct quantum chemical calculations predict Neel temperatures exceeding 100 K for the case of Mn.
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Keywords
Spin-exchange interactions , Pyrophosphate , (VO)(2)P2O7 , Challenges , Devices , Room
Citation
Tiana, D., Hendon, C. H. and Walsh, A. (2014) 'Ligand design for long-range magnetic order in metal-organic frameworks', Chemical Communications, 50(90), pp. 13990-13993. doi: 10.1039/c4cc06433j
Link to publisher’s version
http://pubs.rsc.org/en/content/articlepdf/2014/cc/c4cc06433j
URI
https://hdl.handle.net/10468/6419
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Chemistry - Journal Articles
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© The Royal Society of Chemistry 2014. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence