Real-time nondestructive methods for examining battery electrode materials

dc.contributor.authorGrant, Alex
dc.contributor.authorO'Dwyer, Colm
dc.contributor.funderIrish Research Councilen
dc.date.accessioned2023-03-08T14:51:07Z
dc.date.available2023-03-08T14:51:07Z
dc.date.issued2023-03
dc.date.updated2023-03-07T09:57:10Z
dc.description.abstractWith the importance of Li-ion and emerging alternative batteries to our electric future, predicting new sustainable materials, electrolytes, and complete cells that safely provide high performance, long life, and energy dense capability is critically important. Understanding the interface, the microstructure of materials, and the nature of electrolytes and factors that affect or limit long-term performance is key to new battery chemistries, cell form factors, and alternative materials. The electrochemical processes `that cause these changes are also difficult to probe because of their metastability and lifetimes, which can be of nanosecond to sub-nanosecond time domains. Consequently, developing and adapting high-resolution, nondestructive methods to capture these processes proves challenging, requiring state-of-the-art techniques. Recent progress is very promising, where optical spectroscopies, synchrotron radiation techniques, and energy-specific atom probe tomography and microscopy methods are just some of the approaches that are unraveling the true internal behavior of battery cells in real-time. In this review, we overview many of the most promising nondestructive methods developed in recent years to assess battery material properties, interfaces, processes, and reactions under operando conditions similar in electrodes and full cells.en
dc.description.sponsorshipIrish Research Council (Grant No. IRCLA/2019/118)en
dc.description.statusPeer revieweden
dc.description.versionPublished Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.articleid011312en
dc.identifier.citationGrant, A. and O’Dwyer, C. (2023) ‘Real-time nondestructive methods for examining battery electrode materials’, Applied Physics Reviews, 10(1), 011312 (38pp). doi: 10.1063/5.0107386en
dc.identifier.doi10.1063/5.0107386en
dc.identifier.endpage38en
dc.identifier.issued1en
dc.identifier.journaltitleApplied Physics Reviewsen
dc.identifier.startpage1en
dc.identifier.urihttps://hdl.handle.net/10468/14292
dc.identifier.volume10en
dc.language.isoenen
dc.publisherAmerican Institute of Physicsen
dc.relation.urihttps://aip.scitation.org/doi/full/10.1063/5.0107386
dc.rights© 2023, Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http:// creativecommons.org/licenses/by/4.0/).en
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectOptical propertiesen
dc.subjectSynchrotron radiationen
dc.subjectOptical spectroscopyen
dc.subjectOperando spectroscopyen
dc.subjectPhotonic crystalsen
dc.subjectElectrodesen
dc.subjectElectrochemistryen
dc.subjectTomographyen
dc.subjectNuclear magnetic resonance spectroscopyen
dc.subjectBatteriesen
dc.titleReal-time nondestructive methods for examining battery electrode materialsen
dc.typeArticle (peer-reviewed)en
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