Recent applications of gallium and gallium halides as reagents in organic synthesis

dc.contributor.authorGupta, Manoj K.
dc.contributor.authorO'Sullivan, Timothy P.
dc.contributor.funderEuropean Commissionen
dc.date.accessioned2016-03-01T12:49:03Z
dc.date.available2016-03-01T12:49:03Z
dc.date.issued2013-10-28
dc.date.updated2015-09-07T12:12:39Z
dc.description.abstractThis review highlights the application of gallium metal and gallium halides as reagents in organic synthesis. Owing to their unique catalytic properties, gallium trihalides are considered effective Lewis acids which can activate several functional groups under extremely mild conditions. Gallium halides have been successfully employed as Lewis acid catalysts in various organic transformations such as alkylation, allylation, radical reactions, cycloaddition reactions, Friedel-Craft’s reactions and various coupling reactions. This review seeks to update organic chemists about the potential application of gallium halides in the synthesis of a wide variety of chemical building blocks.en
dc.description.sponsorshipEuropean Commission (Marie Curie Actions: International Incoming Fellowship (IIF))en
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationGUPTA, M. K. & O'SULLIVAN, T. P. 2013. Recent applications of gallium and gallium halides as reagents in organic synthesis. RSC Advances, 3, 25498-25522. http://dx.doi.org/10.1039/C3RA42316Fen
dc.identifier.doi10.1039/c3ra42316f
dc.identifier.endpage25522en
dc.identifier.issn2046-2069
dc.identifier.issued48en
dc.identifier.journaltitleRSC Advancesen
dc.identifier.startpage25498en
dc.identifier.urihttps://hdl.handle.net/10468/2415
dc.identifier.volume3en
dc.language.isoenen
dc.publisherRoyal Society of Chemistryen
dc.relation.urihttp://pubs.rsc.org/en/content/articlepdf/2013/ra/c3ra42316f
dc.rights© The Royal Society of Chemistry 2013en
dc.subjectAlpha,beta-unsaturated carbonyl compoundsen
dc.subjectCatalyzed coupling reactionen
dc.subjectBeta-chlorovinyl ketonesen
dc.subjectFacile synthesisen
dc.subjectNaphthalene derivativesen
dc.subjectSkeletal reorganizationen
dc.subject2-substituted indolesen
dc.subjectMediated allylationen
dc.subjectGaCl3-promoted ethenylationen
dc.titleRecent applications of gallium and gallium halides as reagents in organic synthesisen
dc.typeArticle (peer-reviewed)en
Files
Original bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
Revised_Manuscript.pdf
Size:
1.54 MB
Format:
Adobe Portable Document Format
Description:
Accepted Version
License bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
license.txt
Size:
2.71 KB
Format:
Item-specific license agreed upon to submission
Description: