Pyrrolidinium containing Ionic liquid electrolytes for Li-based batteries

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dc.contributor.authorMcGrath, Louise M.
dc.contributor.authorRohan, James F.
dc.contributor.funderScience Foundation Irelanden
dc.contributor.funderEuropean Regional Development Funden
dc.contributor.funderHorizon 2020en
dc.date.accessioned2021-01-26T12:47:43Z
dc.date.available2021-01-26T12:47:43Z
dc.date.issued2020-12-18
dc.date.updated2021-01-26T12:04:24Z
dc.description.abstractIonic liquids are potential alternative electrolytes to the more conventional solid-state options under investigation for future energy storage solutions. This review addresses the utilization of IL electrolytes in energy storage devices, particularly pyrrolidinium-based ILs. These ILs offer favorable properties, such as high ionic conductivity and the potential for high power drain, low volatility and wide electrochemical stability windows (ESW). The cation/anion combination utilized significantly influences their physical and electrochemical properties, therefore a thorough discussion of different combinations is outlined. Compatibility with a wide array of cathode and anode materials such as LFP, V2O5, Ge and Sn is exhibited, whereby thin-films and nanostructured materials are investigated for micro energy applications. Polymer gel electrolytes suitable for layer-by-layer fabrication are discussed for the various pyrrolidinium cations, and their compatibility with electrode materials assessed. Recent advancements regarding the modification of typical cations such a 1-butyl-1-methylpyrrolidinium, to produce ether-functionalized or symmetrical cations is discussed.en
dc.description.statusPeer revieweden
dc.description.versionPublished Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.articleid6002en
dc.identifier.citationMcGrath, L. M. and Rohan, J. F. (2020) 'Pyrrolidinium Containing Ionic Liquid Electrolytes for Li-Based Batteries', Molecules, 25(24), 6002 (33 pp). doi: 10.3390/molecules25246002en
dc.identifier.doi10.3390/molecules25246002en
dc.identifier.endpage33en
dc.identifier.issn1420-3049
dc.identifier.issued24en
dc.identifier.journaltitleMoleculesen
dc.identifier.startpage1en
dc.identifier.urihttps://hdl.handle.net/10468/10966
dc.identifier.volume25en
dc.language.isoenen
dc.publisherMDPIen
dc.relation.projectinfo:eu-repo/grantAgreement/SFI/SFI Research Centres/13/RC/2077/IE/CONNECT: The Centre for Future Networks & Communications/en
dc.relation.projectinfo:eu-repo/grantAgreement/EC/H2020::RIA/730957/EU/European Infrastructure Powering the Internet of Things/EnABLESen
dc.relation.urihttps://www.mdpi.com/1420-3049/25/24/6002
dc.rights© 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0)en
dc.rights.urihttp://creativecommons.org/licenses/by/4.0en
dc.subjectAnodeen
dc.subjectCathodeen
dc.subjectElectrolyteen
dc.subjectEnergy storageen
dc.subjectIonic liquidsen
dc.subjectLithium ion batteriesen
dc.subjectLithium metal batteriesen
dc.subjectPolymer gel electrolyteen
dc.subjectPyrrolidiniumen
dc.titlePyrrolidinium containing Ionic liquid electrolytes for Li-based batteriesen
dc.typeArticle (peer-reviewed)en
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