Fabrication of a sensitive amperometric sensor for NADH and H2O2 using palladium nanoparticles-multiwalled carbon nanotube nanohybrid

dc.contributor.authorHamidi, Hassan
dc.contributor.authorHaghighi, Behzad
dc.contributor.funderInstitute for Advanced Studies in Basic Sciencesen
dc.contributor.funderIslamic Azad Universityen
dc.date.accessioned2022-08-31T15:46:08Z
dc.date.available2022-08-31T15:46:08Z
dc.date.issued2016-03-11
dc.date.updated2022-08-31T15:30:19Z
dc.description.abstractPalladium nanoparticles decorated multiwalled carbon nanotubes (PdNPs-MWCNTs) were synthesized and simply cast on the surface of a glassy carbon electrode (GCE) to prepare an amperometric sensor. The fabricated sensor (PdNPs-MWCNTs/GCE) showed excellent electrocatalytic activity towards NADH and H2O2 oxidation and H2O2 reduction. A fast, linear and highly sensitive response was observed for NADH in the concentration range between 0.1 and 200 μM with a detection limit (S/N = 3) of 32 nM. Also, the sensor exhibited fast and sensitive responses (< 2 s) towards H2O2. The sensitivity and detection limit for H2O2 at the operating potential of + 0.35 V were 167 nA μM− 1 cm− 2 and 1.2 μM, respectively and better than those obtained at the operating potential of − 0.25 V (68 nA μM− 1 cm− 2 and 14 μM). Moreover, further modification of the proposed sensor by glucose oxidase led to the fabrication of a glucose biosensor with satisfactory performance.en
dc.description.sponsorshipInstitute for Advanced Studies in Basic Sciences (grant number G2015IASBS119)en
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationHamidi, H. and Haghighi, B. (2016) 'Fabrication of a sensitive amperometric sensor for NADH and H2O2 using palladium nanoparticles-multiwalled carbon nanotube nanohybrid', Materials Science and Engineering: C, 62, pp. 423-428. doi: 10.1016/j.msec.2016.01.058en
dc.identifier.doi10.1016/j.msec.2016.01.058en
dc.identifier.eissn1873-0191
dc.identifier.endpage428en
dc.identifier.issn0928-4931
dc.identifier.journaltitleMaterials Science and Engineering: Cen
dc.identifier.startpage423en
dc.identifier.urihttps://hdl.handle.net/10468/13528
dc.identifier.volume62en
dc.language.isoenen
dc.publisherElsevier B.V.en
dc.rights© 2016, Elsevier B.V. All rights reserved. This manuscript version is made available under the CC BY-NC-ND 4.0 license.en
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subjectElectrocatalysis, NADHen
dc.subjectGlucose biosensoren
dc.subjectHydrogen peroxideen
dc.subjectMultiwalled carbon nanotubesen
dc.subjectPalladium nanoparticlesen
dc.titleFabrication of a sensitive amperometric sensor for NADH and H2O2 using palladium nanoparticles-multiwalled carbon nanotube nanohybriden
dc.typeArticle (peer-reviewed)en
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