Fabrication of a sensitive amperometric sensor for NADH and H2O2 using palladium nanoparticles-multiwalled carbon nanotube nanohybrid
dc.contributor.author | Hamidi, Hassan | |
dc.contributor.author | Haghighi, Behzad | |
dc.contributor.funder | Institute for Advanced Studies in Basic Sciences | en |
dc.contributor.funder | Islamic Azad University | en |
dc.date.accessioned | 2022-08-31T15:46:08Z | |
dc.date.available | 2022-08-31T15:46:08Z | |
dc.date.issued | 2016-03-11 | |
dc.date.updated | 2022-08-31T15:30:19Z | |
dc.description.abstract | Palladium nanoparticles decorated multiwalled carbon nanotubes (PdNPs-MWCNTs) were synthesized and simply cast on the surface of a glassy carbon electrode (GCE) to prepare an amperometric sensor. The fabricated sensor (PdNPs-MWCNTs/GCE) showed excellent electrocatalytic activity towards NADH and H2O2 oxidation and H2O2 reduction. A fast, linear and highly sensitive response was observed for NADH in the concentration range between 0.1 and 200 μM with a detection limit (S/N = 3) of 32 nM. Also, the sensor exhibited fast and sensitive responses (< 2 s) towards H2O2. The sensitivity and detection limit for H2O2 at the operating potential of + 0.35 V were 167 nA μM− 1 cm− 2 and 1.2 μM, respectively and better than those obtained at the operating potential of − 0.25 V (68 nA μM− 1 cm− 2 and 14 μM). Moreover, further modification of the proposed sensor by glucose oxidase led to the fabrication of a glucose biosensor with satisfactory performance. | en |
dc.description.sponsorship | Institute for Advanced Studies in Basic Sciences (grant number G2015IASBS119) | en |
dc.description.status | Peer reviewed | en |
dc.description.version | Accepted Version | en |
dc.format.mimetype | application/pdf | en |
dc.identifier.citation | Hamidi, H. and Haghighi, B. (2016) 'Fabrication of a sensitive amperometric sensor for NADH and H2O2 using palladium nanoparticles-multiwalled carbon nanotube nanohybrid', Materials Science and Engineering: C, 62, pp. 423-428. doi: 10.1016/j.msec.2016.01.058 | en |
dc.identifier.doi | 10.1016/j.msec.2016.01.058 | en |
dc.identifier.eissn | 1873-0191 | |
dc.identifier.endpage | 428 | en |
dc.identifier.issn | 0928-4931 | |
dc.identifier.journaltitle | Materials Science and Engineering: C | en |
dc.identifier.startpage | 423 | en |
dc.identifier.uri | https://hdl.handle.net/10468/13528 | |
dc.identifier.volume | 62 | en |
dc.language.iso | en | en |
dc.publisher | Elsevier B.V. | en |
dc.rights | © 2016, Elsevier B.V. All rights reserved. This manuscript version is made available under the CC BY-NC-ND 4.0 license. | en |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | en |
dc.subject | Electrocatalysis, NADH | en |
dc.subject | Glucose biosensor | en |
dc.subject | Hydrogen peroxide | en |
dc.subject | Multiwalled carbon nanotubes | en |
dc.subject | Palladium nanoparticles | en |
dc.title | Fabrication of a sensitive amperometric sensor for NADH and H2O2 using palladium nanoparticles-multiwalled carbon nanotube nanohybrid | en |
dc.type | Article (peer-reviewed) | en |
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