Supercritical fluid growth of porous carbon nanocages

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dc.contributor.authorLi, Zhonglai
dc.contributor.authorJaroniec, Mietek
dc.contributor.authorPapakonstantinou, Pagona
dc.contributor.authorTobin, Joseph M.
dc.contributor.authorVohrer, Uwe
dc.contributor.authorKumar, Shailesh
dc.contributor.authorAttard, Gary
dc.contributor.authorHolmes, Justin D.
dc.contributor.funderSixth Framework Programmeen
dc.contributor.funderEnterprise Irelanden
dc.contributor.funderIntel Corporationen
dc.date.accessioned2019-07-11T15:26:24Z
dc.date.available2019-07-11T15:26:24Z
dc.date.issued2007-05-24
dc.date.updated2019-06-28T16:12:10Z
dc.description.abstractCarbon nanocages, with remarkably large mesoporous volumes, have been synthesized by the deposition of p-xylene over a Co/Mo catalyst in supercritical carbon dioxide. Nanocages with diameters ranging between 10 and 60 nm were synthesized at temperatures between 650 and 750 °C. The surface area and pore volume of the nanocages produced was found to depend on the reaction temperature and pressure employed. In particular, carbon nanocages with a pore volume of up to 5.8 cm3 g-1 and a BET surface area of 1240 m2 g-1 were readily synthesized at a temperature of 650 °C and a pressure of 10.34 MPa. The high pore volume and surface area of the carbon nanocages synthesized makes them ideal materials for use as inert adsorbents and catalytic supports.en
dc.description.sponsorshipEuropean Commission (European Union under the DESYGN-IT project (STREP Project No. 505626-1)); Enterprise Ireland (Project No. IP/2004/0183); Intel Corporation (Intel Ireland)en
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationLi, Z., Jaroniec, M., Papakonstantinou, P., Tobin, J. M., Vohrer, U., Kumar, S., Attard, G. and Holmes, J. D. (2007) 'Supercritical Fluid Growth of Porous Carbon Nanocages', Chemistry of Materials, 19(13), pp. 3349-3354. doi: 10.1021/cm070767ren
dc.identifier.doi10.1021/cm070767ren
dc.identifier.endpage3354en
dc.identifier.issn0897-4756
dc.identifier.issued13en
dc.identifier.journaltitleChemistry of Materialsen
dc.identifier.startpage3349en
dc.identifier.urihttps://hdl.handle.net/10468/8146
dc.identifier.volume19en
dc.language.isoenen
dc.publisherAmerican Chemical Society, ACSen
dc.relation.urihttps://pubs.acs.org/doi/abs/10.1021/cm070767r
dc.rights© 2007 American Chemical Society. This document is the Accepted Manuscript version of a Published Work that appeared in final form in Chemistry of Materials, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/cm070767ren
dc.subjectPorous materialsen
dc.subjectAdsorbentsen
dc.subjectCarbonen
dc.subjectCarbon dioxideen
dc.subjectPressure effectsen
dc.subjectSupercritical fluidsen
dc.subjectSynthesis (chemical)en
dc.subjectXyleneen
dc.subjectCarbon nanocagesen
dc.subjectCatalytic supportsen
dc.subjectCo/Mo catalysten
dc.subjectP-xyleneen
dc.subjectPore volumeen
dc.titleSupercritical fluid growth of porous carbon nanocagesen
dc.typeArticle (peer-reviewed)en
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