A procedure to identify natural arsenic sources, applied in an affected area in North Rhine-Westphalia, Germany

dc.contributor.authorBanning, Andre
dc.contributor.authorColdewey, Wilhelm G.
dc.contributor.authorGöbel, Patricia
dc.contributor.funderAbteilung für Abfallwirtschaft und Umweltkoordination, Kreis Coesfelen
dc.date.accessioned2021-12-08T13:20:17Z
dc.date.available2021-12-08T13:20:17Z
dc.date.issued2008-05-10
dc.date.updated2021-11-23T15:29:34Z
dc.description.abstractThe aim of the study was to identify the geogenic source for elevated arsenic (As) concentrations recently discovered in soils of the Heubach plain, North Rhine-Westphalia, Germany. Therefore, a catalogue of conditions that an As source has to fulfil in order to be considered as geogenic was formulated, including the source’s linkage to the sink, its mineralogy, As total content, As mobilization potential, groundwater redox conditions and As output. Accordingly, mineralogical, geo- and hydrochemical investigations were carried out, including X-ray diffractometry, microscopy, ICP-OES and AAS analysis and a sequential extraction procedure. Paleo bog iron ores (PBIOs) of Tertiary age, occurring within unconsolidated sands (Haltern-layers, Santonian–Lower Campanian), and glauconitic marlstones (Dülmen-layers, Lower Campanian) were examined. Results indicate that output from the PBIOs is responsible for the elevated As levels. Accounting their diverse mineralogy, five types of PBIOs were defined. Type-dependent, they at least partly fulfil all of the formulated requirements. The relations and behaviour of As sources and sinks in space and time could be clarified for the area of interest. The approach presented in this paper may offer a tool for identifying natural As sources worldwide.en
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationBanning, A., Coldewey, W.G. and Göbel, P. (2009) ‘A procedure to identify natural arsenic sources, applied in an affected area in North Rhine-Westphalia, Germany’, Environmental Geology, 57(4), pp. 775-777. doi: 10.1007/s00254-008-1355-4en
dc.identifier.doi10.1007/s00254-008-1355-4en
dc.identifier.endpage787en
dc.identifier.issn0943-0105
dc.identifier.issued4en
dc.identifier.journaltitleEnvironmental Geologyen
dc.identifier.startpage775en
dc.identifier.urihttps://hdl.handle.net/10468/12333
dc.identifier.volume57en
dc.language.isoenen
dc.publisherSpringeren
dc.relation.urihttps://link.springer.com/article/10.1007/s00254-008-1355-4
dc.rights© Springer-Verlag Berlin Heidelberg 2008. This is a post-peer-review, pre-copyedit version of an article published in Environmental Geology. The final authenticated version is available online at: https://doi.org/10.1007/s00254-008-1355-4en
dc.subjectArsenic sourceen
dc.subjectBog iron oreen
dc.subjectGermanyen
dc.subjectHaltern-layersen
dc.subjectMobilization potentialen
dc.subjectRedox conditionsen
dc.titleA procedure to identify natural arsenic sources, applied in an affected area in North Rhine-Westphalia, Germanyen
dc.typeArticle (peer-reviewed)en
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