Access to this article is restricted until 12 months after publication by request of the publisher.. Restriction lift date: 2021-05-15
Surface modification of rutile TiO2 with alkaline-earth oxide nanoclusters for enhanced oxygen evolution
| dc.check.date | 2021-05-15 | |
| dc.check.info | Access to this article is restricted until 12 months after publication by request of the publisher. | en |
| dc.contributor.author | Rhatigan, Stephen | |
| dc.contributor.author | Sokalu, E. | |
| dc.contributor.author | Nolan, Michael | |
| dc.contributor.author | Colón, G. | |
| dc.contributor.funder | Vicepresidencia de Investigación Científica y Técnica, Spain | en |
| dc.contributor.funder | Science Foundation Ireland | en |
| dc.contributor.funder | Horizon 2020 | en |
| dc.date.accessioned | 2020-07-28T11:15:19Z | |
| dc.date.available | 2020-07-28T11:15:19Z | |
| dc.date.issued | 2020-05-15 | |
| dc.date.updated | 2020-07-28T10:50:58Z | |
| dc.description.abstract | The oxygen (O2) evolution reaction (OER) is accepted as the bottleneck in the overall water splitting and has seen intense interest. In this work, we prepared rutile TiO2 modified with nanoclusters of alkaline-earth metal oxides for the OER. Photocatalytic OER was performed over rutile TiO2 surface-modified with alkaline-earth oxide nanoclusters, namely, CaO and MgO. The O2 evolution activity is notably enhanced for MgO-modified systems at low loadings and a combination of characterization and first-principles simulations allows interpretation of the role of the nanocluster modification in improving the photocatalytic performance of alkaline-earth-modified rutile TiO2. At such low loadings, the nanocluster modifiers would be small, and this facilitates a close correlation with theoretical models. Structural and surface characterizations of the modified systems indicate that the integrity of the rutile phase is maintained after modification. However, charge-carrier separation is strongly affected by the presence of surface nanoclusters. This improved performance is related to surface features such as higher ion dispersion and surface hydroxylation, which are also discussed with first-principles simulations. The modified systems are reducible so that Ti3+ ions will be present. Water dissociation is favorable at cluster and interfacial sites of the stoichiometric and reduced modified surfaces. Pathways to water oxidation at interfacial sites of reduced MgO-modified rutile TiO2 are identified, requiring an overpotential of 0.68 V. In contrast, CaO-modified systems required overpotentials in excess of 0.85 V for the reaction to proceed. | en |
| dc.description.sponsorship | Vicepresidencia de Investigación Científica y Técnica, Spain (Project PCIN-2017-056 from the M-ERA.Net programme); Science Foundation Ireland (Grant SFI/16/M-ERA/ 3418 (RATOCAT)) | en |
| dc.description.status | Peer reviewed | en |
| dc.description.version | Accepted Version | en |
| dc.format.mimetype | application/pdf | en |
| dc.identifier.citation | Rhatigan, S., Sokalu, E., Nolan, M. and Colón, G. (2020) 'Surface modification of rutile TiO2 with alkaline-earth oxide nanoclusters for enhanced oxygen evolution', ACS Applied Nano Materials, 3(6), pp. 6017-6033. doi: 10.1021/acsanm.0c01237 | en |
| dc.identifier.doi | 10.1021/acsanm.0c01237 | en |
| dc.identifier.eissn | 2574-0970 | |
| dc.identifier.endpage | 6033 | en |
| dc.identifier.issued | 6 | en |
| dc.identifier.journaltitle | ACS Applied Nano Materials | en |
| dc.identifier.startpage | 6017 | en |
| dc.identifier.uri | https://hdl.handle.net/10468/10315 | |
| dc.identifier.volume | 3 | en |
| dc.language.iso | en | en |
| dc.publisher | ACS Publications | en |
| dc.relation.project | info:eu-repo/grantAgreement/SFI/SFI US Ireland R&D Partnership/14/US/E2915/IE/SusChEM: Using theory-driven design to tailor novel nanocomposite oxides for solar fuel production/ | en |
| dc.relation.project | info:eu-repo/grantAgreement/EC/H2020::ERA-NET-Cofund/685451/EU/ERA-NET for materials research and innovation/M-ERA.NET 2 | en |
| dc.rights | © 2020, American Chemical Society. This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Nano Materials after technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/abs/10.1021/acsanm.0c01237 | en |
| dc.subject | TiO2 | en |
| dc.subject | Surface modification | en |
| dc.subject | O2 evolution | en |
| dc.subject | Alkaline-earth oxide nanocluster | en |
| dc.subject | Photocatalysis | en |
| dc.title | Surface modification of rutile TiO2 with alkaline-earth oxide nanoclusters for enhanced oxygen evolution | en |
| dc.type | Article (peer-reviewed) | en |