NiF2 nanorod arrays for supercapattery applications

Shinde, N. M.; Shinde, P. V.; Yun, J. M.; Gunturu, K. C.; Mane, R. S.; O'Dwyer, Colm; Kim, K. H.

NiF2 nanorod arrays for supercapattery applications

dc.contributor.author	Shinde, N. M.
dc.contributor.author	Shinde, P. V.
dc.contributor.author	Yun, J. M.
dc.contributor.author	Gunturu, K. C.
dc.contributor.author	Mane, R. S.
dc.contributor.author	O'Dwyer, Colm
dc.contributor.author	Kim, K. H.
dc.contributor.funder	National Research Foundation of Korea	en
dc.contributor.funder	Science Foundation Ireland	en
dc.date.accessioned	2020-05-11T14:33:49Z
dc.date.available	2020-05-11T14:33:49Z
dc.date.issued	2020-03-11
dc.date.updated	2020-05-11T11:39:21Z
dc.description.abstract	A electrode for energy storage cells is possible directly on Ni foam, using a simple reduction process to form NiF2 nanorod arrays (NA). We demonstrate NiF2@Ni NA for a symmetric electrochemical supercapattery electrode. With an areal specific capacitance of 51 F cm–2 at 0.25 mA cm–2 current density and 94% cycling stability, a NiF2@Ni electrode can exhibit supercapattery behavior, a combination of supercapacitor and battery-like redox. The symmetric electrochemical supercapattery delivers 31 W h m–2 energy density and 797 W m–2 power density with 83% retention in a 1 M KOH electrolyte, constituting a step toward manufacturing a laboratory-scale energy storage device based on metal halides. Producing self-grown hierarchically porous nanostructured electrodes on three-dimensional metal foams by displacement reactions may be useful for other metal halides as electrodes for supercapacitors, supercapatteries, and lithium-ion batteries.	en
dc.description.sponsorship	National Research Foundation of Korea (Global Frontier Program through the Global Frontier Hybrid Interface Materials(GFHIM) of the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT & Future Planning (2013 M3A6B1078874), the National Core Research Centre (NCRC) grant 2015M3A6B1065262);	en
dc.description.status	Peer reviewed	en
dc.description.version	Published Version	en
dc.format.mimetype	application/pdf	en
dc.identifier.citation	Shinde, N. M., Shinde, P. V., Yun, J. M., Gunturu K. C., Mane R. S., O'Dwyer, C., Kim K. H. (2020) 'NiF2 Nanorod Arrays for Supercapattery Applications', ACS Omega, 5 (17), pp. 9768-9774. doi: 10.1021/acsomega.9b04219	en
dc.identifier.doi	10.1021/acsomega.9b04219	en
dc.identifier.endpage	9774	en
dc.identifier.issn	2470-1343
dc.identifier.issued	17	en
dc.identifier.journaltitle	ACS Omega	en
dc.identifier.startpage	9768	en
dc.identifier.uri	https://hdl.handle.net/10468/9908
dc.identifier.volume	5	en
dc.language.iso	en	en
dc.publisher	American Chemical Society	en
dc.relation.project	info:eu-repo/grantAgreement/SFI/SFI Investigator Programme/14/IA/2581/IE/Diffractive optics and photonic probes for efficient mouldable 3D printed battery skin materials for portable electronic devices/	en
dc.relation.uri	https://pubs.acs.org/doi/abs/10.1021/acsomega.9b04219
dc.rights	© 2020 American Chemical Society. This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License, which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.	en
dc.rights.uri	https://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html	en
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject	Redox reactions	en
dc.subject	Electrical properties	en
dc.subject	Electrodes	en
dc.subject	Nanorods	en
dc.subject	Materials	en
dc.title	NiF2 nanorod arrays for supercapattery applications	en
dc.type	Article (peer-reviewed)	en