Asymmetric oxidation of sulfides

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dc.contributor.authorO'Mahony, Graham E.
dc.contributor.authorFord, Alan
dc.contributor.authorMaguire, Anita R.
dc.date.accessioned2016-08-16T14:43:23Z
dc.date.available2016-08-16T14:43:23Z
dc.date.issued2012-10-16
dc.date.updated2016-08-16T13:58:56Z
dc.description.abstractThis review discusses synthesis of enantiopure sulfoxides through the asymmetric oxidation of prochiral sulfides. The use of metal complexes to promote asymmetric sulfoxidation is described in detail, with a particular emphasis on the synthesis of biologically active sulfoxides. The use of non-metal-based systems, such as oxaziridines, chiral hydroperoxides and peracids, as well as enzyme-catalyzed sulfoxidations is also examined.en
dc.description.statusPeer revieweden
dc.description.versionSubmitted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationO'Mahony, G. E., Ford, A. and Maguire, A. R. (2013) 'Asymmetric oxidation of sulfides'. Journal of Sulfur Chemistry, 34(3), pp. 301-341. http://dx.doi.org/10.1080/17415993.2012.725247en
dc.identifier.doi10.1080/17415993.2012.725247
dc.identifier.endpage341en
dc.identifier.issn1741-5993
dc.identifier.issn1741-6000
dc.identifier.issued3en
dc.identifier.journaltitleJournal of Sulfur Chemistryen
dc.identifier.startpage301en
dc.identifier.urihttps://hdl.handle.net/10468/2996
dc.identifier.volume34en
dc.language.isoenen
dc.publisherTaylor and Francisen
dc.rights© 2013 Taylor and Francis Group, LLC. This is a Submitted Manuscript of an article published by Taylor & Francis in Journal of Sulfur Chemistry on 16 Oct 2012, available online: http://www.tandfonline.com/10.1080/17415993.2012.725247.en
dc.subjectSulfide oxidationen
dc.subjectSulfoxidesen
dc.subjectAsymmetric synthesisen
dc.subjectEnantioselective synthesisen
dc.subjectMetal-based catalystsen
dc.subjectAlkyl aryl sulfidesen
dc.subjectChiral schiff-basesen
dc.subjectHelminthosporium species NRRL-4671en
dc.subjectOptically-active sulfoxidesen
dc.subjectBenzyl methyl sulfoxidesen
dc.subjectAqueous hydrogen-peroxideen
dc.subjectTert-butyl hydroperoxideen
dc.subjectTwin coronet porphyrinsen
dc.subjectMandelic-acid complexen
dc.subjectBovine serum-albuminen
dc.titleAsymmetric oxidation of sulfidesen
dc.typeArticle (peer-reviewed)en
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