Assessment of integration of methane-reduced ceria chemical looping CO2/H2O splitting cycle to an oxy-fired power plant

Simple item page
dc.contributor.authorFarooqui, Azharuddinen
dc.contributor.authorBose, Archishmanen
dc.contributor.authorBoaro, Martaen
dc.contributor.authorLlorca, Jordien
dc.contributor.authorSantarelli, Massimoen
dc.date.accessioned2023-10-18T11:26:34Z
dc.date.available2023-10-18T11:26:34Z
dc.date.issued2020-02-18en
dc.description.abstractIn this paper, we investigated the effect of reaction kinetics and moving bed reactors for chemical looping (CO2/H2O) splitting unit (CL) that produces syngas and fed back to the power plant to gain the efficiency loss due to carbon capture. The reduction reactor (RED) produces methane is partially oxidized to make syngas and reducing the non-stoichiometric ceria which is transported to oxidation reactor (OXI) where the flue gases (CO2 and H2O) split to produce syngas. We developed the kinetics for methane reduced ceria and CO2/H2O splitting in a tubular reactor for an operating temperature range of (900–1100 °C) for different methane concentration which yielded to Avrami-Erofeev (AE3) model fits well for both redox reaction with different reaction constants. A moving bed reactors system is developed representing RED and OXI reactors of CL unit with kinetics hooked to the model in Aspen Plus with FORTRAN code. The effect of thermodynamics and the kinetics of redox reaction was investigated in the proposed integrated plant. The CL unit efficiency obtained is 42.8% for kinetic-based CL unit compares to 64% for thermodynamic based CL unit. However, the maximum available efficiency of the proposed layout lowered as 50.9% for kinetic-based CL unit plant compare to than 61.5% for thermodynamic based CL unit. However, the proposed plant shows an improvement in the energy efficiency penalty from 11.3% to 3.8% after CCS.en
dc.description.statusPeer revieweden
dc.description.versionAccepted Versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationFarooqui, A., Bose, A., Boaro, M., Llorca, J. and Santarelli, M. (2020) 'Assessment of integration of methane-reduced ceria chemical looping CO2/H2O splitting cycle to an oxy-fired power plant', International Journal of Hydrogen Energy, 45(11), pp.6184-6206. doi: 10.1016/j.ijhydene.2019.12.182en
dc.identifier.doi10.1016/j.ijhydene.2019.12.182en
dc.identifier.endpage6206en
dc.identifier.issn0360-3199en
dc.identifier.issued11en
dc.identifier.journaltitleInternational Journal of Hydrogen Energyen
dc.identifier.startpage6184en
dc.identifier.urihttps://hdl.handle.net/10468/15132
dc.identifier.volume45en
dc.language.isoenen
dc.publisherElsevier B.V.en
dc.rights© 2020, Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. This manuscript version is made available under the CC BY-NC-ND 4.0 license.en
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subjectChemical loopingen
dc.subjectCO2/H2O splittingen
dc.subjectKineticsen
dc.subjectExperimentalen
dc.subjectSystem analysisen
dc.subjectMoving bed reactorsen
dc.titleAssessment of integration of methane-reduced ceria chemical looping CO2/H2O splitting cycle to an oxy-fired power planten
dc.typeArticle (peer-reviewed)en
oaire.citation.issue11en
oaire.citation.volume45en
Files
Original bundle
Now showing 1 - 2 of 2
Thumbnail Image
Name:
Paper_exp_sys.pdf
Size:
1.89 MB
Format:
Adobe Portable Document Format
Description:
Accepted Version
Download
Thumbnail Image
Name:
1-s2.0-S036031991934755X-mmc1.docx
Size:
1.07 MB
Format:
Microsoft Word XML
Description:
Supplementary Data
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
2.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Environmental Research Institute - Journal Articles